Diffuse phase transition and relaxor behavior in (PbLa)TiO3 thin films

被引:40
作者
Bhaskar, S [1 ]
Majumder, SB [1 ]
Katiyar, RS [1 ]
机构
[1] Univ Puerto Rico, Dept Phys, Rio Piedras, PR 00931 USA
关键词
D O I
10.1063/1.1481981
中图分类号
O59 [应用物理学];
学科分类号
摘要
Room-temperature micro-Raman scattering and temperature-dependent dielectric measurements were carried out on sol-gel-derived ferroelectric Pb1-xLaxTi1-x/4O3 (PLT x=0.05-0.30) thin films. Results indicate that the crystal structure and the electrical properties of PLT films were strongly influenced by the La contents. The dielectric properties of PLT thin films were studied in the temperature range of 80-700 K and frequencies in the range of 1 kHz-1 MHz. Results show that PLT thin films undergo normal-to-relaxor ferroelectric transformation with 30 at. % La contents. The observed relaxor behavior is established in terms of diffuse phase transition characteristics and Vogel-Fulcher relationship. (C) 2002 American Institute of Physics.
引用
收藏
页码:3997 / 3999
页数:3
相关论文
共 26 条
[11]   B-site vacancy as the origin of spontaneous normal-to-relaxor ferroelectric transitions in La-modified PbTiO3 [J].
Kim, TY ;
Jang, HM .
APPLIED PHYSICS LETTERS, 2000, 77 (23) :3824-3826
[12]   RELAXATION POLARIZATION OF PBMG1-3NB2-3O3(PMN) - FERROELECTRIC WITH A DIFFUSED PHASE-TRANSITION [J].
KIRILLOV, VV ;
ISUPOV, VA .
FERROELECTRICS, 1973, 5 (1-2) :3-9
[13]   Phase formations and ferroelectric properties of PLT thin films by MOCVD [J].
Lee, SS ;
Kim, HG .
INTEGRATED FERROELECTRICS, 1996, 12 (2-4) :83-&
[14]   The influence of defects on first-order structural phase transitions [J].
Levanyuk, AP ;
Minyukov, SA ;
Vallade, M .
JOURNAL OF PHYSICS-CONDENSED MATTER, 1997, 9 (25) :5313-5320
[15]  
LIN CH, 1995, APPL PHYS LETT, V75, P2485
[16]   Investigations on sol-gel derived lanthanum doped lead titanate (PLT) films [J].
Majumder, SB ;
Bhaskar, S ;
Dobal, PS ;
Katiyar, RS .
INTEGRATED FERROELECTRICS, 1999, 23 (1-4) :127-148
[17]   Investigations on the optical properties of sol-gel derived lanthanum doped lead titanate thin films [J].
Majumder, SB ;
Jain, M ;
Katiyar, RS .
THIN SOLID FILMS, 2002, 402 (1-2) :90-98
[18]  
QU B, 1994, PHYS REV B, V52, P3621
[19]   PULSED EXCIMER-LASER ABLATION OF (PB,LA)TIO3 THIN-FILMS FOR DYNAMIC RANDOM-ACCESS MEMORY DEVICES [J].
RAO, GM ;
KRUPANIDHI, SB .
APPLIED PHYSICS LETTERS, 1994, 64 (12) :1591-1593
[20]  
SCOTT JF, 1998, FERROELECTRICS REV, V1, P1, DOI DOI 10.1080/10584589808202046