Catalyst-free, visible-light-promoted S-H insertion reaction between thiols and α-diazoesters

被引：29
|
作者：
Yang, Jingya [1 ]
Wang, Ganggang [1 ]
Chen, Shuwen [1 ]
Ma, Ben [1 ]
Zhou, Hongyan [1 ,2 ]
Song, Menghui [1 ]
Liu, Cai [1 ]
Huo, Congde [1 ]
机构：
[1] Northwest Normal Univ, Coll Chem & Chem Engn, Lanzhou 730070, Peoples R China
[2] Gansu Agr Univ, Coll Sci, Lanzhou 730070, Peoples R China
来源：
ORGANIC & BIOMOLECULAR CHEMISTRY | 2020年 / 18卷 / 46期
基金：
中国国家自然科学基金;
关键词：
BOND FORMATION; DIAZO-COMPOUNDS; C-S; ETHYL DIAZOACETATE; CARBENE-TRANSFER; N-H; METAL; FUNCTIONALIZATION; ACTIVATION; THIOETHERS;
D O I：
10.1039/d0ob02006k
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A visible-light-promoted S-H insertion reaction between thiols and alpha -diazoesters was developed. The reaction proceeded smoothly at room temperature with a broad substrate scope, affording various thioethers in moderate to excellent yields. The catalyst- and additive-free nature, sustainable energy source and mild reaction conditions make this strategy more eco-friendly.
引用
收藏
页码：9494 / 9498
页数：5
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