Photoluminescent metal-organic coordination polymer incorporating one-dimensional silver chains

被引：38

作者：

Luo, Geng-Geng ^{[1
]}

Sun, Di ^{[1
]}

Xu, Qin-Juan ^{[1
]}

Zhang, Na ^{[1
]}

Huang, Rong-Bin ^{[1
]}

Lin, LiRong ^{[1
]}

Zheng, Lan-Sun ^{[1
,2
]}

机构：

[1] Xiamen Univ, Dept Chem, Xiamen 361005, Peoples R China

[2] Xiamen Univ, State Key Lab Phys Chem Solid Surfaces, Xiamen 361005, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2009年 / 12卷 / 05期

基金：

中国国家自然科学基金;

关键词：

Silver(1); 2-Aminopyrimidine; Benzene-1,3,5-tricarboxylic acid; Metal-organic coordination polymer; Crystal structure; Ag center dot center dot center dot Ag interactions; Photoluminescence; CLOSED-SHELL INTERACTIONS; RAY CRYSTAL-STRUCTURES; STRUCTURAL DIVERSITY; AG-I; 3-DIMENSIONAL NETWORK; COMPLEXES; ACID; ARCHITECTURE; PYRIMIDINE; FRAMEWORKS;

D O I：

10.1016/j.inoche.2009.03.007

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Solution phase reaction of AgNO3 with a mixture of benzene-1,3,5-tricarboxylic acid (H3BTC) and heterocyclic 2-aminopyrimidine (APYM) under the ammoniacal conditions gives rise to a novel metal-organic coordination polymer Ag-3(BTC)(APYM)(2) (1). The structure of 1 possesses a unique three-dimensional (3D) framework with one-dimensional channels surrounded by carboxylato-supported Ag-Ag dimers, Ag-Ag chains, fully deprotonated [BTC](3-) and APYM ligands. Moreover, 1 exhibits strong blue photoluminescence maximized at 464 nm at room temperature (lambda(ex) = 383 nm) and upon cooling to 77 K, the emission spectrum seems narrowly red-shifted. (c) 2009 Elsevier B.V. All rights reserved.

引用

页码：436 / 439

页数：4

共 68 条

[21] Hagrman PJ, 1999, ANGEW CHEM INT EDIT, V38, P2639
[22] Coordination networks of 3,3'-dicyanodiphenylacetylene and silver(I) salts: Structural diversity through changes in ligand conformation and counterion
Hirsch, KA
Wilson, SR
Moore, JS
[J]. INORGANIC CHEMISTRY, 1997, 36 (14) : 2960 - 2968
[23] Preparation and crystal structure of tetraaqua-bis(hydrogenopyridine-2,3(di carboxylate)bis(pyridine-2,3-dicarboxylate)hexa silver(I) [Ag-6(C7H4NO4)(2)(C7H3NO4)(2)(H2O)(4)](n)
Jaber, F
Charbonnier, F
Faure, R
[J]. POLYHEDRON, 1996, 15 (17) : 2909 - 2913
[24] Metal-organic frameworks
James, SL
[J]. CHEMICAL SOCIETY REVIEWS, 2003, 32 (05) : 276 - 288
[25] Co-ordination engineering:: when can one speak of an "understanding"?: Case study of the multidentate ligand 2,2′-dimethyl-4,4′-bipyrimidine
Janiak, C
Uehlin, L
Wu, HP
Klüfers, P
Piotrowski, H
Scharmann, TG
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1999, (17): : 3121 - 3131
[26] A versatile family of interconvertible microporous chiral molecular frameworks: The first example of ligand control of network chirality
Kepert, CJ
Prior, TJ
Rosseinsky, MJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (21) : 5158 - 5168
[27] Unusual manifestation of closed-shell interactions in silver(I) complexes:: Crystal structure of catena-bis(4-aminobenzoato)disilver(I) acetone solvate with ligand unsupported chains of repeated rhombohedral Ag4 units
Kristiansson, O
[J]. INORGANIC CHEMISTRY, 2001, 40 (20) : 5058 - +
[28] ABSORPTION AND EMISSION-SPECTRUM OF [ZN4O(ACETATE)6]
KUNKELY, H
VOGLER, A
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (17) : 1204 - 1205
[29] Self-assembly of discrete cyclic nanostructures mediated by transition metals
Leininger, S
Olenyuk, B
Stang, PJ
[J]. CHEMICAL REVIEWS, 2000, 100 (03) : 853 - 907
[30] Design and synthesis of an exceptionally stable and highly porous metal-organic framework
Li, H
Eddaoudi, M
O'Keeffe, M
Yaghi, OM
[J]. NATURE, 1999, 402 (6759) : 276 - 279

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