Preparation of phthalocyanine(3-) species as bulk material by reduction of the dichloro(phthalocyaninato)antimony(V) complex cation

被引：16

作者：

Zahir, MH ^{[1
]}

Kagaya, Y ^{[1
]}

Isago, H ^{[1
]}

Furubayashi, T ^{[1
]}

机构：

[1] Natl Inst Mat Sci, Tsukuba, Ibaraki 3050047, Japan

来源：

INORGANICA CHIMICA ACTA | 2004年 / 357卷 / 09期

关键词：

antimony complex; elemental silver; reduction; bulk material;

D O I：

10.1016/j.ica.2004.02.032

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

By reduction of dichloro(phthalocyaninato)antimony(V) complex, [Sb(pc)Cl-2](+) (pc(2-) = phthalocyaninate, C32H16N82-), its pc(3-) species has been prepared as bulk material using elemental silver as the electron donor. One electron reduction of [Sb(pc)Cl,]+ proceeded without any side reaction. The obtained pc3- species has been characterized by its ESR, electronic absorption, infra-red, and mass spectra. The electronic absorption spectrum of the [Sb(pe(3-.))Cl-2] species was identical with that of the known spectro-electrochemically studied [Sb(pc(3-.))Cl-2]. The first infra-red spectrum of the pc(3-) species of metallophthalocyanine is reported and indicates that the structural change upon the reduction is insignificant. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：2755 / 2758

页数：4

共 21 条

[1]

[Anonymous], PHTHAL PR A

[2]

BOBROVSKII AP, 1973, RUSS J PHYS CHEM, V47, P983

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