Catalytic C-H Borylation Using Iron Complexes Bearing 4,5,6,7-Tetrahydroisoindol-2-ide-Based PNP-Type Pincer Ligand

被引：26

作者：

Kato, Takeru ^{[1
]}

Kuriyama, Shogo ^{[1
]}

Nakajima, Kazunari ^{[2
]}

Nishibayashi, Yoshiaki ^{[1
]}

机构：

[1] Univ Tokyo, Sch Engn, Dept Syst Innovat, Bunkyo Ku, Tokyo 1138656, Japan

[2] Univ Tokyo, Sch Engn, Frontier Res Ctr Energy & Resources, Bunkyo Ku, Tokyo 1138656, Japan

来源：

CHEMISTRY-AN ASIAN JOURNAL | 2019年 / 14卷 / 12期

关键词：

C-H borylation; heterocycles; iron; pincer ligand; ACTIVATION; DEHYDROGENATION; DINITROGEN; BACKBONE; INSIGHTS; ALKYNES;

D O I：

10.1002/asia.201900501

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Catalytic C-H borylation has been reported using newly designed iron complexes bearing a 4,5,6,7-tetrahydroisoindol-2-ide-based PNP pincer ligand. The reaction tolerated various five-membered heteroarenes, such as pyrrole derivatives, as well as six-membered aromatic compounds, such as toluene. Successful examples of the iron-catalyzed sp(3) C-H borylation of anisole derivatives were also presented.

引用

页码：2097 / 2101

页数：5

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