A comparative study of polychlorinated alkanes as standards for the determination of C10-C13 polychlorinated paraffines in fish samples

被引：45
作者：
Coelhan, M [1 ]
Saraci, M [1 ]
Parlar, H [1 ]
机构：
[1] Tech Univ Munich, Chair Chem Tech Anal, D-85350 Freising, Germany
来源：
CHEMOSPHERE | 2000年 / 40卷 / 06期
关键词：
D O I：
10.1016/S0045-6535(99)00444-0
中图分类号：
X [环境科学、安全科学];
学科分类号：
08 ; 0830 ;
摘要：
Fish samples of different origins have been analysed with short column gas chromatography-electron capture negative ion/mass spectrometry (SCGC/ECNI-MS). The influence of standards composed from different polychlorinated alkanes on the quantification of short chain polychlorinated paraffines (CP) was studied. Concentration values varied very differently with the response of the standards depending on their chlorination degree. The results show, that technical CP products should not be used as standard in most cases, because the composition of polychlorinated alkanes in fish is different from sample to sample. (C) 2000 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：685 / 689
页数：5
相关论文
共 13 条
  • [1] ASINGER F, 1959, BER DTSCH CHEM GES, V92, P3084
  • [2] *BER UMW ALTST, 1993, GES EUTSCH CHEM CHLO
  • [3] COMPARATIVE TOXICITY AND CARCINOGENICITY OF 2 CHLORINATED PARAFFINS IN F344/N RATS AND B6C3F1 MICE
    BUCHER, JR
    ALISON, RH
    MONTGOMERY, CA
    HUFF, J
    HASEMAN, JK
    FARNELL, D
    THOMPSON, R
    PREJEAN, JD
    [J]. FUNDAMENTAL AND APPLIED TOXICOLOGY, 1987, 9 (03): : 454 - 468
  • [4] CHLORINATED PARAFFINS AND THE ENVIRONMENT .1. ENVIRONMENTAL OCCURRENCE
    CAMPBELL, I
    MCCONNELL, G
    [J]. ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1980, 14 (10) : 1209 - 1214
  • [5] Determination of short chain polychlorinated paraffins in fish samples by short column GC/ECNI-MS
    Coelhan, M
    [J]. ANALYTICAL CHEMISTRY, 1999, 71 (20) : 4498 - 4505
  • [6] Coelhan M, 1998, FRESEN ENVIRON BULL, V7, P353
  • [7] HARDIE DWF, 1964, KIRKOTHMER ENCY CHEM, V5, P231
  • [8] JANSSON B, 1993, ENVIRON TOXICOL CHEM, V12, P1163
  • [9] A CONTRIBUTION TO THE QUANTIFICATION OF TOXAPHENE RESIDUES IN FISH OILS
    LACH, G
    STANDECKE, U
    PLETSCH, B
    XU, L
    PARLAR, H
    [J]. ZEITSCHRIFT FUR LEBENSMITTEL-UNTERSUCHUNG UND-FORSCHUNG, 1991, 192 (05): : 440 - 444
  • [10] THE USE OF THE BIVALVE MYTILUS-EDULIS AS A TEST ORGANISM FOR BIOCONCENTRATION STUDIES .2. THE BIOCONCENTRATION OF 2 C-14-LABELED CHLORINATED PARAFFINS
    RENBERG, L
    TARKPEA, M
    SUNDSTROM, G
    [J]. ECOTOXICOLOGY AND ENVIRONMENTAL SAFETY, 1986, 11 (03) : 361 - 372
12