Environmental Memory of Polymer Networks under Stress

被引:41
|
作者
Quitmann, Dominik [1 ]
Gushterov, Nikola [2 ]
Sadowski, Gabriele [2 ]
Katzenberg, Frank [1 ]
Tiller, Joerg C. [1 ]
机构
[1] TU Dortmund, Dept Bio & Chem Engn, Chair Biomat & Polymer Sci, D-44221 Dortmund, Germany
[2] TU Dortmund, Dept Bio & Chem Engn, Lab Thermodynam, D-44221 Dortmund, Germany
关键词
NATURAL-RUBBER; CRYSTALS; STRAIN;
D O I
10.1002/adma.201305698
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Generally reversible stimuli-responsive materials do not memorize the stimulus. In this study we describe an example in which stretched and constrained semi-crystalline polymer networks respond to solvent gases with stress and simultaneously memorize the concentration and the chemical nature of the solvent itself in their microstructure (see figure). This written solvent signature can even be deleted by temperature.
引用
收藏
页码:3441 / 3444
页数:4
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