Synthesis and Modular Structural Architectures of Mineralogically Inspired Novel Complex Pb Oxyhalides

被引：26

作者：

Siidra, Oleg I. ^{[1
]}

Zinyakhina, Diana O. ^{[1
]}

Zadoya, Anastasiya I. ^{[1
]}

Krivovichev, Sergey V. ^{[1
]}

Turner, Rick W. ^{[1
]}

机构：

[1] St Petersburg State Univ, Dept Crystallog, St Petersburg 199034, Russia

来源：

INORGANIC CHEMISTRY | 2013年 / 52卷 / 21期

关键词：

II; CRYSTAL-STRUCTURE; LEAD-OXIDE CHLORIDES; OXYCHLORIDE MINERALS; CHEMISTRY; MENDIPITE; OXOHALIDES; PB3O2CL2; ASISITE; BLOCKS; ANALOG;

D O I：

10.1021/ic402066h

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Three novel Pb oxyhalides, Pb-3[O10Pb20](GeO4)(4)Cl-10 (1), [O16Pb22][OPb](OH)I-10(I,Br)(H2O) (2), and Pb5.5Si0.5O6Cl (3), have been prepared by high-temperature solid-state reactions (1 and 3) and hydrothermal method (2). The structure of 1 is based upon novel [O10Pb20](20+) layers of edge- and corner-sharing oxocentered OPb4 tetrahedra with cavities occupied by the GeO4 tetrahedral anions. The interlayer space contains low-occupied Pb sites and Cl- anions. The structure of 2 contains unique [O16Pb22][12+] layers of edge-sharing OPb4 tetrahedra with X- ions (X = I, Br) in and in between the layers. The structure of 3 is the first example of the Pb oxyhalide with the 3:1 ratio between the O-Pb and X sheets (X = halide). The unprecedented structure topologies and architectures observed in the title compounds are closely related to those observed in rare natural Pb oxyhalides that have no synthetic analogues to date.

引用

页码：12799 / 12805

页数：7

共 52 条

[1] New [PbBi2O4][Bi2O2]Cl2 and [PbnBi10-nO13][Bi2O2]nCl4+n Series by Association of Sizable Subunits: Relationship with Arppe's Compound Bi24O31Cl10 and Luminescence Properties [J].

Aliev, A. ;

Olchowka, J. ;

Colmont, M. ;

Capoen, E. ;

Wickleder, C. ;

Mentre, O. .

INORGANIC CHEMISTRY, 2013, 52 (15) :8427-8435

[2]

[Anonymous], 1996, CRYSTAL STRUCTURE I

[3]

AURIVILLIUS B, 1982, CHEM SCRIPTA, V19, P97

[4]

AURIVILLIUS B, 1983, CHEM SCRIPTA, V22, P5

[5]

BEDLIVY D, 1982, AM MINERAL, V67, P833

[6] QUADRATIC PBO-ALPHA MONOXIDE .1. DESCRIPTION OF THE FERROELASTIC STRUCTURAL TRANSITION [J].

BOHER, P ;

GARNIER, P ;

GAVARRI, JR ;

HEWAT, AW .

JOURNAL OF SOLID STATE CHEMISTRY, 1985, 57 (03) :343-350

[7] Crystal structure refinement of sahlinite, Pb14(AsO4)2O9Cl4 [J].

Bonaccorsi, E ;

Pasero, M .

MINERALOGICAL MAGAZINE, 2003, 67 (01) :15-21

[8] Modular Approach as Applied to the Description, Prediction, and Targeted Synthesis of Bismuth Oxohalides with Layered Structures [J].

Charkin, D. O. .

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2008, 53 (13) :1977-1996

[9] Synthesis of novel lead-molybdenum and lead-tungsten oxyhalides with the pinalite structure, Pb3MoO5Cl2 and Pb3WO5Br2 [J].

Charkin, Dmitri O. ;

Lightfoot, Philip .

AMERICAN MINERALOGIST, 2006, 91 (11-12) :1918-1921

[10] Visible-Light-Promoted Stereoselective Alkylation by Combining Heterogeneous Photocatalysis with Organocatalysis [J].

Cherevatskaya, Maria ;

Neumann, Matthias ;

Fueldner, Stefan ;

Harlander, Christoph ;

Kuemmel, Susanne ;

Dankesreiter, Stephan ;

Pfitzner, Arno ;

Zeitler, Kirsten ;

Koenig, Burkhard .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 51 (17) :4062-4066

← 1 2 3 4 5 6 →