Solid-State Synthesis and Photocatalytic Activity of Polyterthiophene Derivatives/TiO2 Nanocomposites

被引：41

作者：

Jamal, Ruxangul ^{[1
,2
]}

Osman, Yakupjan ^{[1
,2
]}

Rahman, Adalet ^{[1
,2
]}

Ali, Ahmat ^{[1
,2
]}

Zhang, Yu ^{[1
,2
]}

Abdiryim, Tursun ^{[1
,2
]}

机构：

[1] Xinjiang Univ, Key Lab Petr & Gas Fine Chem, Educ Minist China, Coll Chem & Chem Engn, Urumqi 830046, Xinjiang, Peoples R China

[2] Xinjiang Univ, Key Lab Funct Polymers, Urumqi 830046, Xinjiang, Peoples R China

来源：

MATERIALS | 2014年 / 7卷 / 05期

基金：

中国国家自然科学基金;

关键词：

polyterthiophene derivative; nano-TiO2; solid-state method; photocatalyst; METHYLENE-BLUE; SOLAR-CELL; FILM; POLYMERIZATION; DEGRADATION; WATER; TIO2; NANOPARTICLES; POLYTHIOPHENE; PERFORMANCE;

D O I：

10.3390/ma7053786

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Poly(3,4-propylenedioxy-2,2':5', 2 ''-terthiophene)/TiO2 and poly(3,4-(2,2-dimethylenepropylenedioxy)-2,2':5',2 ''-terthiophene)/TiO2 nanocomposites were synthesized by a simple solid-state method. Additionally, the poly(3,4-propylenedioxy thiophene)/TiO2 and poly(3,4-2,2-dimethylenepropylenedioxythiophene)/TiO2 nanocomposites were synthesized in a similar manner for comparison. The structure and morphology were characterized by Fourier transform infrared (FTIR), ultraviolet-visible (UV-Vis) absorption spectroscopy, X-ray diffraction (XRD) and transmission electron microscopy (TEM). The photocatalytic activities of the nanocomposites were examined through the degradation processes of a methylene blue (MB) solution under UV light and sunlight irradiation. The results of FTIR and UV-Vis spectra showed that the composites were successfully synthesized by solid-state method and the poly(3,4-propylenedioxy-2,2': 5', 2 ''-terthiophene)/TiO2 and poly(3,4-(2,2-dimethylenepropylenedioxy)-2,2': 5', 2 ''-terthiophene)/TiO2 nanocomposite had a higher oxidation degree and conjugation length than others. The results also indicated that the TiO2 had no effect on the crystallinity of composites, but was well embedded in the polymer matrix. Additionally, the highest degradation efficiency of 90.5% occurred in the case of the poly(3,4-propylenedioxy-2,2': 5', 2 ''-terthiophene)/TiO2 nanocomposite.

引用

页码：3786 / 3801

页数：16

共 52 条

[1] The effect of solvents and organic acids on the p-doping behaviors of poly(3′,4′-Ethylenedioxy-2,2′:5′,2"-terthiophene) [J].