(2-Benzoylbenzoato-κO)triphenyl(triphenylphosphine oxide-κO)tin(IV)

被引：18

作者：

Diop, Cheikh Abdoul Khadir ^{[1
]}

Toure, Assane

Diop, Libasse

Welter, Richard

机构：

[1] Univ Cheikh Anta Diop, Fac Sci & Tech, Dakar, Senegal

[2] Univ Strasbourg 1, CNRS, Lab DECOMET, UMR 7177, F-67000 Strasbourg, France

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2006年 / 62卷

关键词：

D O I：

10.1107/S160053680604726X

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The structure of the title compound, [Sn(C6H5)(3)(C14H9O3)(C18H15OP)], consists of discrete molecules, in which the monodentate C6H5COC6H4COO- anion and OPPh3 are coordinated to an SnPh3 group, and the tin center is in a trigonal-bipyramidal environment. The axial and equatorial positions of the trigonal bipyramid are occupied by the two O atoms of OPPh3 and RCOO- and three ipso C atoms of the three phenyl rings, respectively.

引用

页码：M3338 / M3340

页数：3

共 15 条

[1] The Cambridge Structural Database: a quarter of a million crystal structures and rising [J].

Allen, FH .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 2002, 58 (3 PART 1) :380-388

[2]

Baul TSB, 2002, J ORGANOMET CHEM, V654, P100

[3] Triphenylphosphine oxide adducts of diphenylantimony(V) and diorganotin(IV) Lewis acids:: structures of SnPh2Cl2•OPPh3, SnPb2Cl2•2OPPh3, SnPh2Br2•OPPh3 and SbPh2Cl3•OPPh3 [J].

Cunningham, D ;

Landers, EM ;

McArdle, P ;

Ní Chonchubhair, N .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2000, 612 (1-2) :53-60

[4]

DAVIES AG, 1982, COMPREHENSIVE ORGANO, V2, P519, DOI DOI 10.1016/B978-008046518-0.00019-2

[5] ON ENANTIOMORPH-POLARITY ESTIMATION [J].

FLACK, HD .

ACTA CRYSTALLOGRAPHICA SECTION A, 1983, 39 (NOV) :876-881

[6]

KHOO LE, 1995, POLYHEDRON, V14, P2281

[7]

MARGION MM, 1976, CRYST STRUCT COMMUN, V5, P493

[8] STRUCTURAL RESEARCHES ON ORGANOTIN (4) COMPOUNDS - SYNTHESIS AND STRUCTURE OF "NITRATOTRIPHENYL(TRIPHENYLPHOSPHINE OXIDE) TIN(4) [J].

NARDELLI, M ;

PELIZZI, C ;

PELIZZI, G .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1976, 112 (03) :263-272

[9]

NONIUS, 1998, COLLECT

[10] Processing of X-ray diffraction data collected in oscillation mode [J].

Otwinowski, Z ;

Minor, W .

MACROMOLECULAR CRYSTALLOGRAPHY, PT A, 1997, 276 :307-326

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