Preparation of chi((2))-inverted waveguides with poled polymers for efficient second-harmonic generation

Modal dispersion phase-matched second harmonic generation is demonstrated in polymer-based waveguides with a nonlinear optical core consisting of two side-chain polymers with different glass-transition temperatures. For an optimized overlap integral, a step like nonlinearity profile (chi((2))-inverted structure) is required across the core thickness. The chi((2))-inverted structure is achieved by two consecutive thermally assisted poling steps above and between the respective glass-transition temperatures, with an opposite poling field in the second poling step. The achieved chi((2))-inverted structure is monitored by in-situ electro-optic measurements and proved by electro-optic and second harmonic generation thermal analysis. Conversion efficiencies up to 7%/Wcm(2) were achieved in first waveguide second-harmonic generation experiments.