Thermal and optical characterization of high purity alpha-octithiophene

被引：59

作者：

Fichou, D ^{[1
]}

Teulade-Fichou, MP ^{[1
]}

Horowitz, G ^{[1
]}

Demanze, F ^{[1
]}

机构：

[1] COLL FRANCE, LAB CHIM INTERACT MOL, F-75005 PARIS, FRANCE

来源：

ADVANCED MATERIALS | 1997年 / 9卷 / 01期

关键词：

D O I：

10.1002/adma.19970090118

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The preparation of high purity alpha-octithiophene (alpha-8T) by vacuum sublimation and the investigation of its optical properties in solution and as thin films and single crystals are reported. alpha-8T is probably the ultimate unsubstituted oligothiophene to be processable as a pure crystalline compound, In addition, the first experimental evidence for unsubstituted alpha-12T (see Figure) is presented.

引用

页码：75 / +

共 32 条

[1]

AKAMICHI H, 1991, APPL PHYS LETT, V58, P1500

[2] CRYSTAL-STRUCTURES, PHASE-TRANSITIONS AND ENERGY CALCULATIONS OF POLY(P-PHENYLENE) OLIGOMERS [J].

BAKER, KN ;

FRATINI, AV ;

RESCH, T ;

KNACHEL, HC ;

ADAMS, WW ;

SOCCI, EP ;

FARMER, BL .

POLYMER, 1993, 34 (08) :1571-1587

[3] OLIGOTHIOPHENES - YET LONGER - SYNTHESIS, CHARACTERIZATION, AND SCANNING-TUNNELING-MICROSCOPY IMAGES OF HOMOLOGOUS, ISOMERICALLY PURE OLIGO(ALKYLTHIOPHENE)S [J].

BAUERLE, P ;

FISCHER, T ;

BIDLINGMEIER, B ;

STABEL, A ;

RABE, JP .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (03) :303-307

[4]

DESTRI S, 1993, ADV MATER, V5, P461

[5] ORGANIC TRANSISTORS - 2-DIMENSIONAL TRANSPORT AND IMPROVED ELECTRICAL CHARACTERISTICS [J].

DODABALAPUR, A ;

TORSI, L ;

KATZ, HE .

SCIENCE, 1995, 268 (5208) :270-271

[6] ORIENTATION AND MOBILITY IN ULTRATHIN OLIGOTHIOPHENE FILMS - UV-VIS, IR AND FLUORESCENCE STUDIES [J].

EGELHAAF, HJ ;

BAUERLE, P ;

RAUER, K ;

HOFFMANN, V ;

OELKRUG, D .

SYNTHETIC METALS, 1993, 61 (1-2) :143-146

[7] LOW-TEMPERATURE OPTICAL-ABSORPTION OF POLYCRYSTALLINE THIN-FILMS OF ALPHA-QUATERTHIOPHENE, ALPHA-SEXITHIOPHENE AND ALPHA-OCTITHIOPHENE, 3 MODEL OLIGOMERS OF POLYTHIOPHENE [J].

FICHOU, D ;

HOROWITZ, G ;

XU, B ;

GARNIER, F .

SYNTHETIC METALS, 1992, 48 (02) :167-179

[8] ALPHA-SEXITHIOPHENE - A NEW PHOTOCHROMIC MATERIAL FOR A PROTOTYPE ULTRAFAST INCOHERENT-TO-COHERENT OPTICAL CONVERTER [J].

FICHOU, D ;

NUNZI, JM ;

CHARRA, F ;

PFEFFER, N .

ADVANCED MATERIALS, 1994, 6 (01) :64-67

[9] Growth and structural characterization of the quasi-2D single crystal of alpha-octithiophene [J].

Fichou, D ;

Bachet, B ;

Demanze, F ;

Billy, I ;

Horowitz, G ;

Garnier, F .

ADVANCED MATERIALS, 1996, 8 (06) :500-+

[10]

FICHOU D, 1996, P INT C SYNTH MET IC

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