Synthesis of blue photoluminescent WS2 quantum dots via ultrasonic cavitation

被引:60
作者
Bayat, A. [1 ]
Saievar-Iranizad, E. [1 ]
机构
[1] Tarbiat Modares Univ, Fac Basic Sci, Dept Phys, Tehran, Iran
关键词
WS2 quantum dot; Probe sonication; Luminescence; Eco-friendly solvent; TUNGSTEN DISULFIDE; LIQUID-EXFOLIATION; OPTICAL-PROPERTIES; BAND-STRUCTURES; MONOLAYER MOS2; NANOSHEETS; NANOPARTICLES; NANOCRYSTALS; FABRICATION;
D O I
10.1016/j.jlumin.2017.01.024
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
Blue photoluminescent WS2 quantum dots (QDs) were synthesized using a simple top-down method from natural raw mineral tungsten disulfide via tip ultrasonication followed by centrifugation in a water ethanol (0.7/03 ratio) as eco-friendly solvent. Cavitation process at a high power (300 W) led to the breaking of bulk WS2 flakes to its quantum dots. The as synthesized WS2 QDs showed blue photoluminescence upon UV excitation. The synthesized WS2 QDs were analysed by UV-vis and photoluminescence spectrophotometry, transmission electron microscopy, atomic force microscopy and X-ray diffraction. According to the transmission electron microscopy images, the size of WS2 QDs was obtained as 5 nm in average. (C) 2017 Published by Elsevier B.V.
引用
收藏
页码:236 / 240
页数:5
相关论文
共 44 条
[1]   Fabrication of blue luminescent MoS2 quantum dots by wet grinding assisted co-solvent sonication [J].
Ali, Junaid ;
Siddiqui, Ghayas Uddin ;
Choi, Kyung Hyun ;
Jang, Yunseok ;
Lee, Kangtaek .
JOURNAL OF LUMINESCENCE, 2016, 169 :342-347
[2]   Site-selective luminescence spectroscopy of bound excitons and local band structure of chlorine intercalated 2H-and 3R-MoS2 polytypes [J].
Anghel, S. ;
Chumakov, Yu ;
Kravtsov, V. ;
Volodina, G. ;
Mitioglu, A. ;
Plochocka, P. ;
Sushkevich, K. ;
Mishina, E. ;
Kulyuk, L. .
JOURNAL OF LUMINESCENCE, 2016, 177 :331-336
[3]   Synthesis, characterization and spectral temperature-dependence of thioglycerol-CdSe nanocrystals [J].
Ben Brahim, Nassim ;
Poggi, Melanie ;
Mohamed, Naim Bel Haj ;
Ben Chaabane, Rafik ;
Haouari, Mohamed ;
Negrerie, Michel ;
Ben Ouada, Hafedh .
JOURNAL OF LUMINESCENCE, 2016, 177 :402-408
[4]   Synthesis of Surface-Functionalized WS2 Nanosheets and Performance as Li-Ion Battery Anodes [J].
Bhandavat, R. ;
David, L. ;
Singh, G. .
JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2012, 3 (11) :1523-1530
[5]   Ultrathin WS2 Nanoflakes as a High-Performance Electrocatalyst for the Hydrogen Evolution Reaction [J].
Cheng, Liang ;
Huang, Wenjing ;
Gong, Qiufang ;
Liu, Changhai ;
Liu, Zhuang ;
Li, Yanguang ;
Dai, Hongjie .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2014, 53 (30) :7860-7863
[6]   Two-Dimensional Nanosheets Produced by Liquid Exfoliation of Layered Materials [J].
Coleman, Jonathan N. ;
Lotya, Mustafa ;
O'Neill, Arlene ;
Bergin, Shane D. ;
King, Paul J. ;
Khan, Umar ;
Young, Karen ;
Gaucher, Alexandre ;
De, Sukanta ;
Smith, Ronan J. ;
Shvets, Igor V. ;
Arora, Sunil K. ;
Stanton, George ;
Kim, Hye-Young ;
Lee, Kangho ;
Kim, Gyu Tae ;
Duesberg, Georg S. ;
Hallam, Toby ;
Boland, John J. ;
Wang, Jing Jing ;
Donegan, John F. ;
Grunlan, Jaime C. ;
Moriarty, Gregory ;
Shmeliov, Aleksey ;
Nicholls, Rebecca J. ;
Perkins, James M. ;
Grieveson, Eleanor M. ;
Theuwissen, Koenraad ;
McComb, David W. ;
Nellist, Peter D. ;
Nicolosi, Valeria .
SCIENCE, 2011, 331 (6017) :568-571
[7]   Synthesis and Optical Properties of Large-Area Single-Crystalline 2D Semiconductor WS2 Monolayer from Chemical Vapor Deposition [J].
Cong, Chunxiao ;
Shang, Jingzhi ;
Wu, Xing ;
Cao, Bingchen ;
Peimyoo, Namphung ;
Qiu, Caiyu ;
Sun, Litao ;
Yu, Ting .
ADVANCED OPTICAL MATERIALS, 2014, 2 (02) :131-136
[8]   Fluorescent MoS2 Quantum Dots: Ultrasonic Preparation, Up-Conversion and Down-Conversion Bioimaging, and Photodynamic Therapy [J].
Dong, Haifeng ;
Tang, Songsong ;
Hao, Yansong ;
Yu, Haizhu ;
Dai, Wenhao ;
Zhao, Guifeng ;
Cao, Yu ;
Lu, Huiting ;
Zhang, Xueji ;
Ju, Huangxian .
ACS APPLIED MATERIALS & INTERFACES, 2016, 8 (05) :3107-3114
[9]   The chemical synthesis in solution and characterization of transition metal dichalcogenide MX2 (M = Mo, W; X = S, Se) nanoparticles [J].
Duphil, D ;
Bastide, S ;
Rouchaud, JC ;
Pastol, JL ;
Legendrel, B ;
Lévy-Clément, C .
NANOTECHNOLOGY, 2004, 15 (07) :828-832
[10]   Synthesis of tungsten disulfide (WS2) nanoflakes for lithium ion battery application [J].
Feng, Chuanqi ;
Huang, Lunfeng ;
Guo, Zaiping ;
Liu, Huakun .
ELECTROCHEMISTRY COMMUNICATIONS, 2007, 9 (01) :119-122