Synthesis, reactivity, and ligand properties of a stable alkyl carbene

被引：156

作者：

Lavallo, V

Mafhouz, J

Canac, Y

Donnadieu, B

Schoeller, WW

Bertrand, G ^{[1
]}

机构：

[1] Univ Calif Riverside, Dept Chem, UCR, CNRS,UMR 2282,Joint Res Chem Lab, Riverside, CA 92521 USA

[2] Univ Bielefeld, Fak Chem, D-33615 Bielefeld, Germany

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2004年 / 126卷 / 28期

关键词：

D O I：

10.1021/ja047503f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Stable tert-butyl diisopropylamino carbene is more nucleophilic but also more electrophilic than diamino carbenes; it undergoes cyclopropanation reactions and easily binds to metal fragments. Copyright © 2004 American Chemical Society.

引用

页码：8670 / 8671

页数：2

共 44 条

[1]

Alder RW, 2002, CARBENE CHEMISTRY, P153

[2] Bis(diisopropylamino)carbene [J].

Alder, RW ;

Allen, PR ;

Murray, M ;

Orpen, AG .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1996, 35 (10) :1121-1123

[3] 3-ETHYL-2-TETRAZO-6-X-BENZO[D]THIAZOLINES AND THEIR REACTIVITY - A CONTRIBUTION TO THE CHEMISTRY OF NUCLEOPHILIC CARBENES [J].

BALLI, H ;

GRUNER, H ;

MAUL, R ;

SCHEPP, H .

HELVETICA CHIMICA ACTA, 1981, 64 (03) :648-656

[4]

Bally T., 2004, REACTIVE INTERMEDIAT, P797

[5] Constructing a stable carbene with a novel topology and electronic framework [J].

Bazinet, P ;

Yap, GPA ;

Richeson, DS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (44) :13314-13315

[6] Synthesis of a transient tropylidene substituted N-heterocyclic carbene (tropNHC):: rearrangement and formation of its gold complex [J].

Böhler, C ;

Stein, D ;

Donati, N ;

Grützmacher, H .

NEW JOURNAL OF CHEMISTRY, 2002, 26 (10) :1291-1295

[7] Stable carbenes [J].

Bourissou, D ;

Guerret, O ;

Gabbaï, FP ;

Bertrand, G .

CHEMICAL REVIEWS, 2000, 100 (01) :39-91

[8] Stable versions of transient push-pull carbenes: Extending lifetimes from nanoseconds to weeks [J].

Buron, C ;

Gornitzka, H ;

Romanenko, V ;

Bertrand, G .

SCIENCE, 2000, 288 (5467) :834-836

[9] Amino-aryl-carbenes:: Alternative ligands for transition metals? [J].

Cattoën, X ;

Gornitzka, H ;

Bourissou, D ;

Bertrand, G .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (05) :1342-1343

[10] CARBENE COMPLEXES .19. OPTICALLY-ACTIVE ELECTRON-RICH OLEFIN-DERIVED CARBENE-TRANSITION-METAL COMPLEXES - CRYSTAL-STRUCTURES OF [RHCL(COD)(C7H12N2)], [RHCL(COD)(C9H16N2)], [RHCL(PPH3)2(C9H18N2)] AND [CO(CO)(NO)(PPH3)(C6H12N2)] [J].

COLEMAN, AW ;

HITCHCOCK, PB ;

LAPPERT, MF ;

MASKELL, RK ;

MULLER, JH .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1985, 296 (1-2) :173-196

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