A new method for atmospheric nitrogen dioxide measurements using the combination of a stripping coil and fluorescence detection

被引：7

作者：

Chen, XY ^{[1
]}

Oro, Y ^{[1
]}

Tanaka, K ^{[1
]}

Takenaka, N ^{[1
]}

Bandow, H ^{[1
]}

机构：

[1] Osaka Prefecture Univ, Grad Sch Engn, Dept Appl Mat Sci, Sakai, Osaka 5998531, Japan

来源：

ANALYTICAL SCIENCES | 2004年 / 20卷 / 07期

关键词：

D O I：

10.2116/analsci.20.1019

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

A new stripping coil for the collection of nitrogen dioxide (NO2) has been developed to increase its versatility and efficiency. Nitrogen dioxide measurements based on quantitative collection through a reaction coil into an alkaline solution has been examined. Nitrogen dioxide is collected in a 0.1 N NaOH solution. This collection system has an efficiency of nearly 100%. The absorbed nitrogen dioxide has been measured by fluorescence detection with sub-ppbv detection limits. The excitation wavelength at 360 nm and the produced emission wavelength at 405 nm were suitable for nitrite ion measurements.

引用

页码：1019 / 1023

页数：5

共 31 条

[1]

[Anonymous], 1996, ATMOSPHERIC CHEM PHY

[2]

[Anonymous], ADV ENV SCI ENG

[3] COMPARISON OF ATMOSPHERIC NITROUS-ACID MEASUREMENTS BY ANNULAR DENUDER AND DIFFERENTIAL OPTICAL-ABSORPTION SYSTEMS [J].

APPEL, BR ;

WINER, AM ;

TOKIWA, Y ;

BIERMANN, HW .

ATMOSPHERIC ENVIRONMENT PART A-GENERAL TOPICS, 1990, 24 (03) :611-616

[4] FLUOROMETRIC-DETERMINATION OF NITRITE [J].

DAMIANI, P ;

BURINI, G .

TALANTA, 1986, 33 (08) :649-652

[5] EVALUATION OF A HIGH-PURITY AND HIGH-STABILITY CONTINUOUS GENERATION SYSTEM FOR NITROUS-ACID [J].

FEBO, A ;

PERRINO, C ;

GHERARDI, M ;

SPARAPANI, R .

ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1995, 29 (09) :2390-2395

[6] A laser induced fluorescence instrument for measuring tropospheric NO2 [J].

Fong, C ;

Brune, WH .

REVIEW OF SCIENTIFIC INSTRUMENTS, 1997, 68 (11) :4253-4262

[7] HOMOGENEOUS CHEMILUMINESCENT MEASUREMENT OF NITRIC OXIDE WITH OZONE - IMPLICATIONS FOR CONTINUOUS SELECTIVE MONITORING OF GASEOUS AIR POLLUTANTS [J].

FONTIJN, A ;

SABADELL, AJ ;

RONCO, RJ .

ANALYTICAL CHEMISTRY, 1970, 42 (06) :575-&

[8]

FUGAS M, 1966, SEP PROC INT C OCC H, V1

[9] PROTOTYPE FAGE DETERMINATION OF NO2 [J].

GEORGE, LA ;

OBRIEN, RJ .

JOURNAL OF ATMOSPHERIC CHEMISTRY, 1991, 12 (03) :195-209

[10] NATIONAL AIR QUALITY STANDARDS FOR AUTOMOTIVE POLLUTANTS - CRITICAL REVIEW [J].

HEUSS, JM ;

NEBEL, GJ ;

COLUCCI, JM .

JOURNAL OF THE AIR POLLUTION CONTROL ASSOCIATION, 1971, 21 (09) :535-&

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