Complexes with a tridentate aroylhydrazone ligand: Microwave solid-state synthesis, crystalline architectures through supramolecular interactions and electrochemical properties

被引：12

作者：

Xu, Suo-Ping ^{[1
,2
]}

Yang, Feng-Lei ^{[1
,2
]}

Zhu, Guang-Zhou ^{[1
,2
]}

Shi, Huan-Le ^{[3
]}

Li, Xiu-Ling ^{[1
,2
]}

机构：

[1] Jiangsu Normal Univ, Sch Chem & Chem Engn, Xuzhou 221116, Jiangsu, Peoples R China

[2] Jiangsu Normal Univ, Jiangsu Key Lab Green Synthet Chem Funct Mat, Xuzhou 221116, Jiangsu, Peoples R China

[3] Lianyungang Henrychem Sci Co Ltd, Lianyungang 222000, Jiangsu, Peoples R China

来源：

POLYHEDRON | 2014年 / 68卷

基金：

中国国家自然科学基金;

关键词：

Transition metal complexes; Microwave solid-state synthesis; Supramolecular interactions; Cyclic voltammetry; COPPER(II) COMPLEXES; COORDINATION POLYMER; FE(III) COMPLEXES; SCHIFF-BASE; PI-STACKING; CU(II); NICKEL(II); ZINC(II); NI(II);

D O I：

10.1016/j.poly.2013.10.013

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of complexes, [CuLCl]center dot 1.5H(2)O (1); [ML2]center dot X (X = 0, M = Cd, 2a; X= DMF, M = Hg, 2b; X = DMF, M = Ni, 2c); [Cu-2(OOCCH3)(2)L-2]center dot 2CH(3)OH (3) have been synthesized by microwave solid-state method with a tridentate aroylhydrazone ligand HL (HL = N-3-salicyloylpyridine-2-carboxamidrazone). All these compounds were characterized by element analysis, IR, X-ray diffraction and electrochemistry. Crystal analysis revealed that the coordination molecules extended to 3D supramolecular networks through plentiful H-bondings and weak molecular interactions between the ligand moieties and solvent molecules. Meanwhile, these compounds displayed diverse metal or ligand localized electrochemical properties. (C) 2013 Elsevier Ltd. All rights reserved.

引用

页码：1 / 9

页数：9

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