This paper presents LIPP measurements of space charge accumulation in 0.5mm thick planar XLPE samples with aluminium electrodes, over the temperature range 30 - 90 degrees C. The applied field strength was 10kV/mm. It was concluded that electrons injected at the cathode are transported to the anode at temperatures above 40 degrees C, and that electron traps cause an accumulation of negative charge immediately adjacent to both cathode and anode. It appears that a concentration of impurity molecules accumulates close to the cathode, and field-assisted thermal ionisation of these molecules generates an immobile positive space charge adjoining the electronic space charge adjacent to the cathode.