Organizing a bis(iminoylnitroxide) diradical into antiferromagnetically coupled chains by co-crystallization with dichloromethane

被引：2

作者：

Akpinar, Handan ^{[1
]}

Schlueter, John A. ^{[2
]}

Lahti, Paul M. ^{[1
]}

机构：

[1] Univ Massachusetts, Dept Chem, Amherst, MA 01003 USA

[2] Natl Sci Fdn, Div Mat Res, Arlington, VA 22230 USA

来源：

CRYSTENGCOMM | 2014年 / 16卷 / 26期

基金：

美国国家科学基金会;

关键词：

CENTER-DOT-NITRO; MAGNETIC-PROPERTIES; MOLECULAR MATERIALS; CRYSTAL-STRUCTURES; BUILDING-BLOCKS; RADICALS; EXCHANGE; IMINO; BIRADICALS; PROPERTY;

D O I：

10.1039/c4ce00207e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

1,3-Bis(4',4',5',5'-tetramethyl-4',5'-dihydro-1'H-imidazol-2'-yl-1'-oxyl)-5-iodobenzene (IPhIN2) forms a co-crystal with dichloromethane (CH2Cl2) and some water, with columnar pi-stacking of radical N-O moieties organized into antiferromagnetically exchange-coupled 1-D chains.

引用

页码：5832 / 5838

页数：7

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