Testing carbon-coated VOx prepared via reaction under autogenic pressure at elevated temperature as Li-insertion materials

被引:142
作者
Odani, Ayelet
Pol, Vilas Ganpat
Pol, Swati Vilas
Koltypin, Maxim
Gedanken, Aharon [1 ]
Aurbach, Doron
机构
[1] Bar Ilan Univ, Ctr Adv Mat & Nanotechnol, Dept Chem, IL-52900 Ramat Gan, Israel
[2] Bar Ilan Univ, Ctr Adv Mat & Nanotechnol, Kanbar Lab Nanomat, IL-52900 Ramat Gan, Israel
[3] Bar Ilan Univ, Dept Chem, IL-52900 Ramat Gan, Israel
关键词
D O I
10.1002/adma.200501611
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
V2O3 nanoparticles covered by a 15 nm thick uniform carbon coating are prepared by reaction under autogenic pressure at elevated temperature of VO(OC2H5)(3) at 700 degrees C. Further oxidation of this material produces carbon-coated V2O5 nanoparticles. Both materials reversibly insert Li (see figure) electrochemically in nonaqueous Li-salt solutions.
引用
收藏
页码:1431 / +
页数:7
相关论文
共 36 条
[1]  
ALEXANDER L, 1962, XRAY DIFFRACTION PRO, P125
[2]   Lithium intercalation in electrodeposited vanadium oxide bronzes [J].
Andrukaitis, E .
JOURNAL OF POWER SOURCES, 2003, 119 :205-210
[3]  
[Anonymous], 1999, Handbook of Battery Materials, DOI DOI 10.1002/9783527611676.CH17
[4]   Lithium-ion intercalation into TiO2-B nanowires [J].
Armstrong, AR ;
Armstrong, G ;
Canales, J ;
García, R ;
Bruce, PG .
ADVANCED MATERIALS, 2005, 17 (07) :862-+
[5]   THE ELECTROCHEMISTRY OF NOBLE-METAL ELECTRODES IN APROTIC ORGANIC-SOLVENTS CONTAINING LITHIUM-SALTS [J].
AURBACH, D ;
DAROUX, M ;
FAGUY, P ;
YEAGER, E .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1991, 297 (01) :225-244
[6]   Second phase effects on the conductivity of non-aqueous salt solutions: "Soggy sand electrolytes" [J].
Bhattacharyya, AJ ;
Maier, J .
ADVANCED MATERIALS, 2004, 16 (9-10) :811-+
[7]   V-Mg-O prepared via a mesoporous pathway: a low-temperature catalyst for the oxidative dehydrogenation of propane to propene [J].
Chao, ZS ;
Ruckenstein, E .
CATALYSIS LETTERS, 2004, 94 (3-4) :217-221
[8]   Noncatalytic and catalytic conversion of ethane over V-Mg oxide catalysts prepared via solid reaction or mesoporous precursors [J].
Chao, ZS ;
Ruckenstein, E .
JOURNAL OF CATALYSIS, 2004, 222 (01) :17-31
[9]   ON THE DELTA-]GAMMA IRREVERSIBLE TRANSFORMATION IN LI//V2O5 SECONDARY BATTERIES [J].
COCCIANTELLI, JM ;
MENETRIER, M ;
DELMAS, C ;
DOUMERC, JP ;
POUCHARD, M ;
BROUSSELY, M ;
LABAT, J .
SOLID STATE IONICS, 1995, 78 (1-2) :143-150
[10]   FORMATION OF THE OMEGA-TYPE PHASE BY LITHIUM INTERCALATION IN (MO, V) OXIDES DERIVING FROM V2O5 [J].
DELMAS, C ;
COGNACAURADOU, H .
JOURNAL OF POWER SOURCES, 1995, 54 (02) :406-410