Sol-gel entrapped chiral rhodium and ruthenium complexes as recyclable catalysts for the hydrogenation of itaconic acid

被引：53
|
作者：
Gelman, F
Avnir, D [1 ]
Schumann, H
Blum, J
机构：
[1] Hebrew Univ Jerusalem, Dept Organ Chem, IL-91904 Jerusalem, Israel
[2] Tech Univ Berlin, Inst Anorgan & Analyt Chem, D-10623 Berlin, Germany
来源：
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 1999年 / 146卷 / 1-2期
关键词：
enantioselective hydrogenation; immobilized catalysts; rhodium; ruthenium; sol-gel;
D O I：
10.1016/S1381-1169(99)00103-X
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Chiral Ru-BINAP, Rh-DIOP and Rh-BPPM complexes have been physically entrapped in sol-gel matrices. The resulting materials are recyclable leach-proof catalysts for enantioselective hydrogenation of itaconic acid. Chiral methylsuccinic acid of o.p. up to 78% is obtained. The complexes, including the water insoluble Ru-BINAP derivatives, react both in organic and in aqueous media. (C) 1999 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：123 / 128
页数：6
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