Structural versatility and luminescent properties in d10 metal ion polymers with 1,4-naphthalenedicarboxylate acid and 4,4′-dipyridyl N,N′-dioxide

被引：15

作者：

An, Bing ^{[1
]}

Zhou, Ruimin ^{[1
]}

Dang, Dongbin ^{[1
]}

Wang, Junli ^{[1
]}

Pan, Hui ^{[1
]}

Bai, Yan ^{[1
]}

机构：

[1] Henan Univ, Inst Mol & Crystal Engn, Sch Chem & Chem Engn, Henan Key Lab Polyoxometalate Chem, Kaifeng 475004, Peoples R China

来源：

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY | 2014年 / 122卷

基金：

中国国家自然科学基金;

关键词：

d(10) Metal ion; Coordination polymer; Crystal structure; Luminescent property; ORGANIC FRAMEWORKS; COORDINATION POLYMERS; CRYSTAL-STRUCTURES; NETWORKS; COMPLEXES; CLUSTERS; CO; PHOTOLUMINESCENCE; MANGANESE(II); DICARBOXYLATE;

D O I：

10.1016/j.saa.2013.11.046

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

Hydrothermal reactions of d(10) metal ions (Cd2+ and Zn2+) with 1,4-naphthalenedicarboxylate acid (1,4-H2NDC) and 4,4'-dipyridyl N,N'-dioxide (4,4'-dpdo) form two three-dimensional grid-like coordination polymers [Cd-2(1,4-NDC)(2)(4,4'-dpdo)center dot H2O 1 and [Zn-4(mu(3)-OH)(2)(1,4-NDC)(3)(H2O)(2)](4,4'-dpdo)center dot 2H(2)O 2. Both coordination polymers were characterized by single crystal X-ray diffraction, IR spectroscopy, XRPD, thermogravimetric and elemental analyses. Polymer 1 exhibits rare alternating arranged 1,4-NDC2- and 4,4'-dpdo spacers between adjacent 1D zigzag chains containing Cd-octahedral coordination geometries. Polymer 2 is constructed from infrequent chair-like [Zn-4(mu(3)-OH)(2)](6+) inorganic SBUs with four- and six-coordination geometries and only 1,4-NDC2- as "single-bridge" and "double-bridges" to form a 3D framework. Both polymers give strong luminescent emissions in the solid state at room temperature. (C) 2013 Elsevier B.V. All rights reserved.

引用

页码：392 / 399

页数：8

共 39 条

[21] Can 4,4′-bipyridine N,N′-dioxide play the same important role as 4,4′-bipyridine in the construction of metal coordination networks and crystal engineering? [J].