Structural versatility and luminescent properties in d10 metal ion polymers with 1,4-naphthalenedicarboxylate acid and 4,4′-dipyridyl N,N′-dioxide

被引:15
作者
An, Bing [1 ]
Zhou, Ruimin [1 ]
Dang, Dongbin [1 ]
Wang, Junli [1 ]
Pan, Hui [1 ]
Bai, Yan [1 ]
机构
[1] Henan Univ, Inst Mol & Crystal Engn, Sch Chem & Chem Engn, Henan Key Lab Polyoxometalate Chem, Kaifeng 475004, Peoples R China
基金
中国国家自然科学基金;
关键词
d(10) Metal ion; Coordination polymer; Crystal structure; Luminescent property; ORGANIC FRAMEWORKS; COORDINATION POLYMERS; CRYSTAL-STRUCTURES; NETWORKS; COMPLEXES; CLUSTERS; CO; PHOTOLUMINESCENCE; MANGANESE(II); DICARBOXYLATE;
D O I
10.1016/j.saa.2013.11.046
中图分类号
O433 [光谱学];
学科分类号
0703 ; 070302 ;
摘要
Hydrothermal reactions of d(10) metal ions (Cd2+ and Zn2+) with 1,4-naphthalenedicarboxylate acid (1,4-H2NDC) and 4,4'-dipyridyl N,N'-dioxide (4,4'-dpdo) form two three-dimensional grid-like coordination polymers [Cd-2(1,4-NDC)(2)(4,4'-dpdo)center dot H2O 1 and [Zn-4(mu(3)-OH)(2)(1,4-NDC)(3)(H2O)(2)](4,4'-dpdo)center dot 2H(2)O 2. Both coordination polymers were characterized by single crystal X-ray diffraction, IR spectroscopy, XRPD, thermogravimetric and elemental analyses. Polymer 1 exhibits rare alternating arranged 1,4-NDC2- and 4,4'-dpdo spacers between adjacent 1D zigzag chains containing Cd-octahedral coordination geometries. Polymer 2 is constructed from infrequent chair-like [Zn-4(mu(3)-OH)(2)](6+) inorganic SBUs with four- and six-coordination geometries and only 1,4-NDC2- as "single-bridge" and "double-bridges" to form a 3D framework. Both polymers give strong luminescent emissions in the solid state at room temperature. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:392 / 399
页数:8
相关论文
共 39 条
  • [1] [Anonymous], 1997, SHELXL 97 PROGRAMS X
  • [2] Synthesis, crystal structures and luminescent properties of two one-dimensional cadmium(II) coordination polymers generated from polydentate Schiff-base ligand
    Bai, Yan
    Wang, Jun-Li
    Dang, Dong-Bin
    Zheng, Yan-Ning
    [J]. SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2012, 97 : 105 - 110
  • [3] Co(II)/Zn(II) Coordination Polymers with Angular Dicarboxylate and Flexible N-Donor Struts: Structural and Photoluminescence Studies
    Bisht, Kamal Kumar
    Suresh, Eringathodi
    [J]. CRYSTAL GROWTH & DESIGN, 2013, 13 (02) : 664 - 670
  • [4] Rational Construction of 3D Pillared Metal-Organic Frameworks: Synthesis, Structures, and Hydrogen Adsorption Properties
    Chang, Ze
    Zhang, Da-Shuai
    Chen, Qiang
    Li, Rui-Fang
    Hu, Tong-Liang
    Bu, Xian-He
    [J]. INORGANIC CHEMISTRY, 2011, 50 (16) : 7555 - 7562
  • [5] Highly-connected, porous coordination polymers based on [M4(μ3-OH)2] (M = CoII and NiII) clusters: different networks, adsorption and magnetic properties
    Chen, Qing
    Xue, Wei
    Lin, Jian-Bin
    Lin, Rui-Biao
    Zeng, Ming-Hua
    Chen, Xiao-Ming
    [J]. DALTON TRANSACTIONS, 2012, 41 (14) : 4199 - 4206
  • [6] Luminescent Functional Metal-Organic Frameworks
    Cui, Yuanjing
    Yue, Yanfeng
    Qian, Guodong
    Chen, Banglin
    [J]. CHEMICAL REVIEWS, 2012, 112 (02) : 1126 - 1162
  • [7] Three-dimensional homochiral manganese-lanthanide frameworks based on chiral camphorates with multi-coordination modes
    Dang, Dong-Bin
    An, Bing
    Bai, Yan
    Zheng, Guang-Shui
    Niu, Jing-Yang
    [J]. CHEMICAL COMMUNICATIONS, 2013, 49 (22) : 2243 - 2245
  • [8] Syntheses, structures, photoluminescence, photocatalysis, and photoelectronic effects of 3D mixed high-connected metal-organic frameworks based on octanuclear and dodecanuclear secondary building units
    Du, Peng
    Yang, Yan
    Yang, Jin
    Liu, Bing-Kun
    Ma, Jian-Fang
    [J]. DALTON TRANSACTIONS, 2013, 42 (05) : 1567 - 1580
  • [9] Ag(I) and Zn(II) coordination polymers with a bulky naphthalene-based dicarboxyl tecton and different 4,4′-bipyridyl-like bridging co-ligands: structural regulation and properties
    Fang, Shao-Ming
    Hu, Min
    Zhang, Qiang
    Du, Miao
    Liu, Chun-Sen
    [J]. DALTON TRANSACTIONS, 2011, 40 (17) : 4527 - 4541
  • [10] Metal-Organic Frameworks: Opportunities for Catalysis
    Farrusseng, David
    Aguado, Sonia
    Pinel, Catherine
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (41) : 7502 - 7513