Metal complex catalyzed oxidations with hydroperoxides: Inner-sphere electron transfer

被引：25

作者：

Moiseeva, NI

Gekhman, AE

Moiseev, II

机构：

[1] RUSSIAN ACAD SCI,NS KURNAKOV GEN & INORGAN CHEM INST,MOSCOW,RUSSIA

[2] RUSSIAN ACAD SCI,NN SEMENOV CHEM PHYS INST,MOSCOW,RUSSIA

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 1997年 / 117卷 / 1-3期

关键词：

vanadium; molybdenum; tungsten; hydrogen peroxide; peroxo complexes; trioxo dianion; singlet dioxygen; ozone; metal complex catalysis; alkene; perfluoroalkenes; arenes; perfluoroarenes; beta-diketonates;

D O I：

10.1016/S1381-1169(96)00417-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The reactions involving electron transfer between peroxidic oxidant and a substrate capable of coordination to a metal atom are reviewed. A metal ion can act as a mediator between the coordinated reactants in such a redox reaction. Oxidation of acetylacetonate and related compounds, singlet dioxygen formation and decomposition of H2O2 to form ozone are discussed as examples.

引用

页码：39 / 55

页数：17

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