Metal complex catalyzed oxidations with hydroperoxides: Inner-sphere electron transfer

被引：25
|
作者：
Moiseeva, NI
Gekhman, AE
Moiseev, II
机构：
[1] RUSSIAN ACAD SCI,NS KURNAKOV GEN & INORGAN CHEM INST,MOSCOW,RUSSIA
[2] RUSSIAN ACAD SCI,NN SEMENOV CHEM PHYS INST,MOSCOW,RUSSIA
来源：
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 1997年 / 117卷 / 1-3期
关键词：
vanadium; molybdenum; tungsten; hydrogen peroxide; peroxo complexes; trioxo dianion; singlet dioxygen; ozone; metal complex catalysis; alkene; perfluoroalkenes; arenes; perfluoroarenes; beta-diketonates;
D O I：
10.1016/S1381-1169(96)00417-7
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The reactions involving electron transfer between peroxidic oxidant and a substrate capable of coordination to a metal atom are reviewed. A metal ion can act as a mediator between the coordinated reactants in such a redox reaction. Oxidation of acetylacetonate and related compounds, singlet dioxygen formation and decomposition of H2O2 to form ozone are discussed as examples.
引用
收藏
页码：39 / 55
页数：17
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