Molecular Rotors and Motors: Recent Advances and Future Challenges

被引:265
作者
Michl, Josef [2 ,3 ]
Sykes, E. Charles H. [1 ]
机构
[1] Tufts Univ, Dept Chem, Medford, MA 02155 USA
[2] Univ Colorado, Dept Chem & Biochem, Boulder, CO 80309 USA
[3] Acad Sci Czech Republ, Inst Organ Chem & Biochem, CR-16610 Prague, Czech Republic
基金
美国国家科学基金会;
关键词
SINGLE-MOLECULE; UNIDIRECTIONAL ROTATION; ELECTRIC-FIELD; DIPOLE CHAINS; DYNAMICS; MOTION; ADSORPTION; CONSTRUCTION; SIMULATION; VISCOSITY;
D O I
10.1021/nn900411n
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
At the "Molecular Rotors and Motors" symposium of the Spring 2009 ACS National Meeting in Salt Lake City (March 22-26), a diverse mix of talks addressed many current issues in the field. Speakers described topics that varied from single-molecule rotors and nanomachines to exquisite synthetic approaches toward building functional materials and mathematical and computational methods aimed at uncovering design opportunities and highlighting the fundamental limitations of molecular motors. While the realization of building useful nanomachines remains far off, a general consensus abounded that investigating biological systems and understanding the implications of the laws of thermodynamics and quantum mechanics for the behavior of nanostructures will help drive important advances in the quest for molecular machinery. Molecular rotors were demonstrated to have practical applications as probes for microviscosity, and many speakers presented experimental studies that indicated that highly directed translation and rotation of individual molecules, as well as interacting dipolar arrays, are just around the corner. While this Nano Focus is not intended to be a comprehensive review of the subject, it will focus on several key advances that were presented at the ACS meeting and highlight future challenges for the field of molecular rotors and motors.
引用
收藏
页码:1042 / 1048
页数:7
相关论文
共 70 条
[1]   Molecular dynamics of surface-moving thermally driven nanocars [J].
Akimov, Alexei V. ;
Nemukhin, Alexander V. ;
Moskovsky, Alexander A. ;
Kolomeisky, Anatoly B. ;
Tour, James M. .
JOURNAL OF CHEMICAL THEORY AND COMPUTATION, 2008, 4 (04) :652-656
[2]   Recording the intramolecular deformation of a 4-legs molecule during its STM manipulation on a Cu(211) surface [J].
Alemani, M ;
Gross, L ;
Moresco, F ;
Rieder, KH ;
Wang, C ;
Bouju, X ;
Gourdon, A ;
Joachim, C .
CHEMICAL PHYSICS LETTERS, 2005, 402 (1-3) :180-185
[3]   Adiabatic operation of a molecular machine [J].
Astumian, R. Dean .
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2007, 104 (50) :19715-19718
[4]   Making molecules into motors [J].
Astumian, RD .
SCIENTIFIC AMERICAN, 2001, 285 (01) :56-64
[5]   Thermodynamics and kinetics of a Brownian motor [J].
Astumian, RD .
SCIENCE, 1997, 276 (5314) :917-922
[6]   A Quantitative Single-Molecule Study of Thioether Molecular Rotors [J].
Baber, Ashleigh E. ;
Tierney, Heather L. ;
Sykes, E. Charles H. .
ACS NANO, 2008, 2 (11) :2385-2391
[7]   Engineering Dislocation Networks for the Directed Assembly of Two-Dimensional Rotor Arrays [J].
Bellisario, Darin O. ;
Baber, Ashleigh E. ;
Tierney, Heather L. ;
Sykes, E. Charles H. .
JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (15) :5895-5898
[8]   A rack-and-pinion device at the molecular scale [J].
Chiaravalloti, Franco ;
Gross, Leo ;
Rieder, Karl-Heinz ;
Stojkovic, Sladjana M. ;
Gourdon, Andre ;
Joachim, Christian ;
Moresco, Francesca .
NATURE MATERIALS, 2007, 6 (01) :30-33
[9]   The dielectric response of chloromethylsilyl and dichloromethylsilyl dipolar rotors on fused silica surfaces [J].
Clarke, LI ;
Horinek, D ;
Kottas, GS ;
Varaksa, N ;
Magnera, TF ;
Hinderer, TP ;
Horansky, RD ;
Michl, J ;
Price, JC .
NANOTECHNOLOGY, 2002, 13 (04) :533-540
[10]   Local field controlled switching in a one-dimensional dipolar array [J].
de Jonge, Jeroen J. ;
Ratner, Mark A. ;
de Leeuw, Simon W. .
JOURNAL OF PHYSICAL CHEMISTRY C, 2007, 111 (09) :3770-3777