Metal-free aerobic oxidative coupling of amines in dimethyl sulfoxide via a radical pathway

被引：26

作者：

Lin, Mu ^{[1
]}

Wang, Zikuan ^{[1
]}

Fang, Huayi ^{[1
]}

Liu, Lianghui ^{[1
]}

Yin, Haolin ^{[1
]}

Yan, Chun-Hua ^{[1
]}

Fu, Xuefeng ^{[1
]}

机构：

[1] Peking Univ, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat Chem & Applicat, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China

来源：

RSC ADVANCES | 2016年 / 6卷 / 13期

基金：

中国博士后科学基金; 美国国家科学基金会;

关键词：

CATALYTIC-SYSTEM; SECONDARY-AMINES; SELECTIVE METHOD; BENZYLIC AMINES; NEAT CONDITIONS; SUPPORTED GOLD; IMINES; TIO2; BENZYLAMINES; NANOCLUSTERS;

D O I：

10.1039/c5ra25434e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Metal-free oxidative coupling of amines is achieved simply by heating their dimethyl sulfoxide (DMSO) solution under oxygen as oxidant without any other catalysts or additives, accompanied by the formation of an equimolar amount of dimethyl sulfone (DMSO2). EPR experiments indicate that the reaction proceeds via a radical pathway. DMSO may play a triple role as solvent, radical initiator and co-reductant.

引用

页码：10861 / 10864

页数：4

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