Derivatives of 1,1′-bis(diphenylphosphino)ferrocene (dppf):: Electrochemistry, complexation and the X-ray structures of 1,1′-bis(diphenylphosphino)osmocene (dppo) and [PdCl2(dppo)]

被引：17
作者：
Martinak, Sarah L.
Sites, Lauren A.
Kolb, Sarah J.
Bocage, Katherine M.
McNamara, William R.
Rheingold, Arnold L.
Golen, James A.
Nataro, Chip [1 ]
机构：
[1] Lafayette Coll, Dept Chem, Easton, PA 18042 USA
[2] Univ Calif San Diego, Dept Chem & Biochem, La Jolla, CA 92093 USA
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2006年 / 691卷 / 17期
关键词：
electrochemistry; cyclic voltammetry; crystal structures; 1,1 '-bis(diphenylphosphino)osmocene; 1,1 '-bis(diphenylarsino)ferrocene; 1,1 '-bis(diphenylphosphinoindenyl)iron;
D O I：
10.1016/j.jorganchem.2006.05.012
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The oxidative electrochemistry of 1,1'-bis(diphenylphosphino)osmocene (dppo) and 1,1'-bis(diphenylarsino)ferrocene (dpaf) was studied in dichloromethane with tetrabutylammonium hexafluorophosphate as the supporting electrolyte. The [MCl2((PP)-P-boolean AND)l (M = Pd or Pt; (PP)-P-boolean AND = dppo or 1,1'-bis(diphenylphosphinoindenyl)iron) complexes were prepared, studied electrochemically and the X-ray structures of dppo and [PdCl2(dppo)] were determined. (c) 2006 Elsevier B.V. All rights reserved.
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页码：3627 / 3632
页数：6
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