Simultaneous analysis of the photocatalytic degradation of polycyclic aromatic hydrocarbons using three-dimensional excitation-emission matrix fluorescence and parallel factor analysis

Polycyclic aromatic hydrocarbons (PAHs) may be photochemically degraded. Monitoring of degradation process of PAHs is carried out by traditional methods, which normally imply time-consuming procedures that do not allow the chemical process to be analyzed in real time. In the present study, photodegradation kinetics of dibenz[a,h]anthracene, benz[a]anthracene, benz[a]pyrene and benz[k]fluorantene were investigated in aqueous solutions under different conditions. A 2(3) factorial design was used for optimizing the degradation process. Fluorescence spectroscopy is a fast, cheap and sensitive analytical method, attractive for use in conjunction with chemometric methods; in this case three-way analytical methodology based on fluorescence excitation-emission matrix (EEM) and parallel factor analysis (PARAFAC) was employed. A four-factor PARAFAC model made it possible to resolve the species presents in the degradation mixture and quantify the relative concentration of the analytes throughout the degradation. Several different parameters, such as core consistency, percentage of fit and correlation coefficients between recovered and reference spectra were employed to determine the suitable number of factors for the PARAFAC model. This new methodology allows us to determine satisfactorily the PAHs concentration during the photodegradation in mixtures of arbitrary composition, representing an interesting alternative to the conventional techniques normally used for the monitoring of degradation reactions. (c) 2006 Elsevier B.V. All rights reserved.