Fe(II) Spin Crossover Molecule-Based Materials

被引：0
作者：
Zhu Dunru [1 ]
Qi Li [1 ]
Cheng Huimin [1 ]
Shen Xuan [1 ]
Lu Wei [1 ]
机构：
[1] Nanjing Univ Technol, State Key Lab Mat Oriented Chem Engn, Coll Chem & Chem Engn, Nanjing 210009, Peoples R China
来源：
PROGRESS IN CHEMISTRY | 2009年 / 21卷 / 06期
关键词：
spin crossover; Fe(II) complexes; LIESST effect; multifunctional materials; ROOM-TEMPERATURE; ELECTRICAL-CONDUCTIVITY; MAGNETIC-PROPERTIES; THERMAL HYSTERESIS; IRON(II) COMPOUNDS; TRANSITION; STATE; CRYSTAL; COMPLEXES; BEHAVIOR;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Spin crossover complex has an ideal molecular bistability in which a single molecule or an assembly of molecules can be used as active elements in novel thermal switches, optical switches or information memory devices. The important progress over the past three years on Fe(II) spin crossover molecule-based materials is reviewed in this paper. These materials include the Fe(II) spin crossover complexes showing a spin transition close to room temperature, the Fe(II) spin crossover compounds with the light-induced excited spin state trapping (LIESST) effect and the multifunctional Fe(II) spin crossover materials with liquid crystalline properties, porous properties or electrical conductivity. The applications and perspectives of the Fe(II) spin crossover molecule-based materials are also discussed.
引用
收藏
页码：1187 / 1198
页数：12
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共 65 条
  • [11] LIGHT-INDUCED EXCITED SPIN STATE TRAPPING IN A TRANSITION-METAL COMPLEX - THE HEXA-1-PROPYLTETRAZOLE-IRON (II) TETRAFLUOROBORATE SPIN-CROSSOVER SYSTEM
    DECURTINS, S
    GUTLICH, P
    KOHLER, CP
    SPIERING, H
    HAUSER, A
    [J]. CHEMICAL PHYSICS LETTERS, 1984, 105 (01) : 1 - 4
  • [12] LIGHT-INDUCED EXCITED-SPIN-STATE TRAPPING IN IRON(II) SPIN-CROSSOVER SYSTEMS - OPTICAL SPECTROSCOPIC AND MAGNETIC-SUSCEPTIBILITY STUDY
    DECURTINS, S
    GUTLICH, P
    HASSELBACH, KM
    HAUSER, A
    SPIERING, H
    [J]. INORGANIC CHEMISTRY, 1985, 24 (14) : 2174 - 2178
  • [13] [Fe(sal2-trien)][Ni(dmit)2]:: towards switchable spin crossover molecular conductors
    Dorbes, S
    Valade, L
    Real, JA
    Faulmann, C
    [J]. CHEMICAL COMMUNICATIONS, 2005, (01) : 69 - 71
  • [14] Towards molecular conductors with a spin-crossover phenomenon:: Crystal structures, magnetic properties and Mossbauer spectra of [Fe(salten)Mepepy][M(dmit)2] complexes
    Faulmann, C
    Dorbes, S
    de Bonneval, WG
    Molnár, G
    Bousseksou, A
    Gomez-Garcia, CJ
    Coronado, E
    Valade, L
    [J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2005, (16) : 3261 - 3270
  • [15] Electrical conductivity and spin crossover: A new achievement with a metal bis dithiolene complex
    Faulmann, Christophe
    Jacob, Kane
    Dorbes, Stephane
    Lampert, Stephane
    Malfant, Isabelle
    Doublet, Marie-Liesse
    Valade, Lydie
    Real, Jose A.
    [J]. INORGANIC CHEMISTRY, 2007, 46 (21) : 8548 - 8559
  • [16] Tunable bistability in a three-dimensional spin-crossover sensory- and memory-functional material
    Galet, A
    Gaspar, AB
    Munoz, MC
    Bukin, GV
    Levchenko, G
    Real, JA
    [J]. ADVANCED MATERIALS, 2005, 17 (24) : 2949 - +
  • [17] Spin crossover in 1D, 2D and 3D polymeric Fe(II) networks
    Garcia, Y
    Niel, V
    Muñoz, MC
    Real, JA
    [J]. SPIN CROSSOVER IN TRANSITION METAL COMPOUNDS I, 2004, 233 : 229 - 257
  • [18] Multifunctionality in spin crossover materials
    Gaspar, AB
    Ksenofontov, V
    Seredyuk, M
    Gütlich, P
    [J]. COORDINATION CHEMISTRY REVIEWS, 2005, 249 (23) : 2661 - 2676
  • [19] First dicyanamide-bridged spin-crossover coordination polymer: Synthesis, structural, magnetic, and spectroscopic studies
    Genre, Caroline
    Jeanneau, Erwann
    Bousseksou, Azzedine
    Luneau, Dominique
    Borshch, Serguei A.
    Matouzenko, Galina S.
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2008, 14 (02) : 697 - 705
  • [20] SPIN TRANSITIONS IN 6-COORDINATE IRON(II) COMPLEXES
    GOODWIN, HA
    [J]. COORDINATION CHEMISTRY REVIEWS, 1976, 18 (03) : 293 - 325
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