A Gold Nanoparticles-Enhanced Carbon Nanotubes Electrochemical Chiral Sensor

被引:12
作者
Chen, Lisha [1 ]
Liu, Shuai [2 ]
Chang, Fengxia [2 ]
Xie, Xia [2 ]
Zhu, Zhiwei [2 ]
机构
[1] Shanghai Tobacco Grp Beijing Cigarette Factory, Beijing 101121, Peoples R China
[2] Peking Univ, Beijing Natl Lab Mol Sci, Coll Chem & Mol Engn, Beijing 100871, Peoples R China
基金
中国国家自然科学基金;
关键词
Carbon nanotube; Gold nanoparticles; Electrochemical chiral sensor; 3; 4-Dihydroxyphenylalanine; Tyrosine; DOPA ENANTIOMERS; LIQUID NANOCOMPOSITE; MASS-SPECTROMETRY; OPTICAL-ACTIVITY; PARTICLE-SIZE; 3,4-DIHYDROXYPHENYLALANINE; RECOGNITION; AMINO; ACID; CYCLODEXTRIN;
D O I
10.1002/elan.201600747
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The field of enantioselective recognition directly using inherently chiral single-walled carbon nanotubes (cSWCNTs) still remains unexplored. Herein, the insertion of size-controlled gold nanoparticles (GNPs) to cSWCNTs brings about superior conductivity, high stability, and excellent electrocatalytic ability, thus an enhanced sensitivity for chiral sensing. The practicability of the GNPs/cSWCNTs based electrochemical sensor was validated by chirally recognizing 3,4-dihydroxyphenylalanine and tyrosine as model molecules.
引用
收藏
页码:955 / 959
页数:5
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