Bifunctional Chiral Organocatalysts in Organic Transformations

被引：45

作者：

Bhadury, Pinaki S. ^{[1
]}

Song, Bao-An ^{[1
]}

Yang, Song ^{[1
]}

Hu, De-Yu ^{[1
]}

Xue, Wei ^{[1
]}

机构：

[1] Guizhou Univ, Ctr Res & Dev Fine Chem, Key Lab Green Pesticide & Agr Bioengn, Minist Educ, Guiyang 550025, Peoples R China

来源：

CURRENT ORGANIC SYNTHESIS | 2009年 / 6卷 / 04期

基金：

中国国家自然科学基金;

关键词：

Asymmetric organocatalysis; axially chiral binaphthyl; Bronsted acid catalyst; chiral thiourea; absolute configuration; synthesis; ENANTIOSELECTIVE MICHAEL ADDITION; FRIEDEL-CRAFTS ALKYLATION; CATALYTIC ASYMMETRIC-SYNTHESIS; BAYLIS-HILLMAN REACTION; STEREOSELECTIVE-SYNTHESIS; 1,3-DICARBONYL COMPOUNDS; THIOUREA ORGANOCATALYST; ALPHA-AMINOPHOSPHONATES; TRANSFER HYDROGENATION; TERTIARY ALCOHOLS;

D O I：

10.2174/157017909789108710

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In continuation to our earlier review, we report herein further development on the organocatalytic approach for the synthesis of enantioenriched organic compounds. Application of synthetic bifunctional chiral organocatalysts with emphasis on Bronsted acid catalyst derived from chiral phosphoric acid derivative, and mechanism of asymmetric catalysis are discussed.

引用

页码：380 / 399

页数：20

共 134 条

[1] The nitro-Mannich reaction and its application to the stereoselective synthesis of 1,2-diamines [J].