Asymmetric Hydrogenation of Cinnamyl Acetate Derivatives with Chiral Iridium Ferrocenyloxazolinylphosphine Complexes

被引：0

作者：

Meng, Xiangyan ^{[1
]}

Li, Xinsheng ^{[1
,2
]}

Xu, Dongcheng ^{[1
,2
]}

机构：

[1] Zhejiang Normal Univ, Dept Chem, Jinhua 321004, Peoples R China

[2] Zhejiang Normal Univ, Inst Phys Chem, Zhejiang Key Lab React Chem Solid Surfaces, Jinhua 321004, Peoples R China

来源：

CHINESE JOURNAL OF ORGANIC CHEMISTRY | 2009年 / 29卷 / 04期

关键词：

asymmetric hydrogenation; iridium; catalyst; planar chirality; olefin; ENANTIOSELECTIVE HYDROGENATION; OLEFINS; LIGANDS;

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A series of chiral iridium Fc-PHOX complexes were readily prepared from Fc-PHOX, [Ir(COD)Cl](2) and NaBArF in high yields, which were proved to be highly efficient catalysts for the enantioselective hydrogenation of (E)-2-methyl-3-phenylallyl acetate derivatives to afford the corresponding products with complete conversions and excellent enantioselectivities (up to 99.5% ee).

引用

页码：629 / 633

页数：5

共 23 条

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