Recent advances in experimental techniques have led to more stable and reliable all-organic electronic devices as displays, rectifiers and transistors. However, a true molecular device has not yet been realized. In the present work we propose a new type of all-organic transistor with novel properties that is within the feasibility of the present technology for organic materials. Based on molecular modeling techniques, we demonstrate that the conductivity of a conjugated polymer chain may be modulated by a static electric field, without chemical doping. This is the first theoretical characterization of an all-organic molecular transistor based on quantum chemical calculations.
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Univ Lorraine Nancy, SRSMC, F-54506 Vandoeuvre Les Nancy, France
CNRS, SRSMC, F-54506 Vandoeuvre Les Nancy, FranceUniv Lorraine Nancy, SRSMC, F-54506 Vandoeuvre Les Nancy, France
Chbibi, Laurent
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Michaux, Catherine
Perpete, Eric A.
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Univ Namur, Unite Chim Phys Theor & Struct, B-5000 Namur, BelgiumUniv Lorraine Nancy, SRSMC, F-54506 Vandoeuvre Les Nancy, France
Perpete, Eric A.
Assfeld, Xavier
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Univ Lorraine Nancy, SRSMC, F-54506 Vandoeuvre Les Nancy, France
CNRS, SRSMC, F-54506 Vandoeuvre Les Nancy, FranceUniv Lorraine Nancy, SRSMC, F-54506 Vandoeuvre Les Nancy, France
Assfeld, Xavier
Monari, Antonio
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Univ Lorraine Nancy, SRSMC, F-54506 Vandoeuvre Les Nancy, France
CNRS, SRSMC, F-54506 Vandoeuvre Les Nancy, FranceUniv Lorraine Nancy, SRSMC, F-54506 Vandoeuvre Les Nancy, France
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STMicroelectronics, Technol R&D, Post Silicon Technol Grp, I-95121 Catania, ItalyUniv Catania, Dipartimento Metodol Fis & Chim Ingn, I-95125 Catania, Italy
La Rosa, Manuela
Nicolosi, Donata
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STMicroelectronics, Technol R&D, Post Silicon Technol Grp, I-95121 Catania, ItalyUniv Catania, Dipartimento Metodol Fis & Chim Ingn, I-95125 Catania, Italy
Nicolosi, Donata
Sicurella, Giovanni
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STMicroelectronics, Technol R&D, Post Silicon Technol Grp, I-95121 Catania, ItalyUniv Catania, Dipartimento Metodol Fis & Chim Ingn, I-95125 Catania, Italy
Sicurella, Giovanni
Umana, Elena
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Univ Catania, Dipartimento Ingn Elettr Elettron & Sistemi, I-95125 Catania, Italy
STMicroelectronics, Technol R&D, Post Silicon Technol Grp, I-95121 Catania, ItalyUniv Catania, Dipartimento Metodol Fis & Chim Ingn, I-95125 Catania, Italy