Birnessite-type manganese dioxide nanoparticles embedded with nitrogen-doped carbon for high-performance supercapacitor

被引:25
作者
Ahamad, Tansir [1 ]
Naushad, Mu [1 ]
Ubaidullah, Mohd [1 ]
Alzaharani, Yahya [1 ]
Alshehri, Saad M. [1 ]
机构
[1] King Saud Univ, Coll Sci, Dept Chem, Riyadh 11451, Saudi Arabia
关键词
MnO2; Carbon materials; Nanoparticles; Nanocomposite; Supercapacitor; HIERARCHICALLY POROUS CARBON; ELECTRODE MATERIALS; NANOSHEETS; NANOWIRES; FRAMEWORK; GROWTH; CLOTH;
D O I
10.1016/j.est.2020.101952
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
In this study, we have fabricated manganese oxide nanoparticles embedded with N-doped carbon (MnO2/NDC) using egg albumin via hydrothermal and post calcination treatment. It was noticed that the MnO2 nanoparticles were grown into the nitrogen doped carbon matrix. As-fabricated NDC and MnO2/NDC show excellent surface area about to 685 m(2)/g and 645 m(2)/g respectively. The SEM and TEM images results revealed that the fabricated birnessite-type MnO2 nanoparticles are uniformly embedded into N-doped graphitic carbon matrix. The asymmetric super capacitor cell (ASC) was fabricated using the NDC and MnO2/NDC nanocomposites as a cathode and anode respectively and separated with whatman filter paper and 1.0 M Na2SO4 was used as electrolyte. The specific capacitance of the asymmetric supercapacitor is determine and found 895 F.g(-1) at 0.5A.g(-1) current density. The fabricated ASC show excellent charge and discharge properties and long term stability. The asymmetric NDC//MnO2/NDC cell supplies an excellent energy density about to 402.5 W h kg(-1) with power density about to 2250 W kg(-1). Therefore, these outcomes support that fabricated nanocomposite can be used as a potential electrode material for supercapacitor application.
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页数:7
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共 59 条
[1]   New antimicrobial epoxy-resin-bearing Schiff-base metal complexes [J].
Ahamad, Tansir ;
Nishat, N. .
JOURNAL OF APPLIED POLYMER SCIENCE, 2008, 107 (04) :2280-2288
[2]   Fabrication of highly porous N/S doped carbon embedded with CuO/CuS nanoparticles for NH3 gas sensing [J].
Ahamad, Tansir ;
Naushad, Mu ;
Alshheri, Saad M. .
MATERIALS LETTERS, 2020, 268
[3]   Fabrication of MoS2/ZnS embedded in N/S doped carbon for the photocatalytic degradation of pesticide [J].
Ahamad, Tansir ;
Naushad, Mu ;
Al-Saeedi, Sameerah, I ;
Almotairi, Sultanah ;
Alshehri, Saad M. .
MATERIALS LETTERS, 2020, 263
[4]   N/S-doped carbon embedded with AgNPs as a highly efficient catalyst for the reduction of toxic organic pollutants [J].
Ahamad, Tansir ;
Naushad, Mu ;
Al-Saeedi, Sameerah, I ;
Alshehri, Saad M. .
MATERIALS LETTERS, 2020, 264
[5]   Synthesis of NiOx@NPC composite for high-performance supercapacitor via waste PET plastic-derived Ni-MOF [J].
Al-Enizi, Abdullah M. ;
Ubaidullah, Mohd ;
Ahmed, Jahangeer ;
Ahamad, Tansir ;
Ahmad, Tokeer ;
Shaikh, Shoyebmohamad F. ;
Naushad, Mu. .
COMPOSITES PART B-ENGINEERING, 2020, 183
[6]   Synthesis and characterization of highly selective and sensitive Sn/SnO2/Ndoped carbon nanocomposite (Sn/SnO2@NGC) for sensing toxic NH3 gas [J].
Al-Enizi, Abdullha M. ;
Naushad, Mu. ;
Al-Muhtaseb, Ala'a H. ;
Ruksana ;
Alshehri, Saad M. ;
Alothman, Z. A. ;
Ahamad, Tansir .
CHEMICAL ENGINEERING JOURNAL, 2018, 345 :58-66
[7]   Fabrication of hybrid nanocomposite derived from chitosan as efficient electrode materials for supercapacitor [J].
Al-Farraj, Eida S. ;
Alhabarah, Ameen N. ;
Ahmad, Jahangeer ;
Al-Enizi, Abdullah M. ;
Naushad, Mu ;
Ubaidullah, Mohd ;
Alshehri, Saad M. ;
Ruksana ;
Ahamad, Tansir .
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES, 2018, 120 :2271-2278
[8]   Biomass based N-doped hierarchical porous carbon nanosheets for all-solid-state supercapacitors [J].
Chen, Mingfeng ;
Yu, Dan ;
Zheng, Xiaozhong ;
Dong, Xiaoping .
JOURNAL OF ENERGY STORAGE, 2019, 21 :105-112
[9]   N-doped carbon quantum dots boost the electrochemical supercapacitive performance and cyclic stability of MoS2 [J].
El Sharkawy, Heba M. ;
Dhmees, Abdelghaffar S. ;
Tamman, A. R. ;
El Sabagh, S. M. ;
Aboushahba, R. M. ;
Allam, Nageh K. .
JOURNAL OF ENERGY STORAGE, 2020, 27
[10]   Preparation of MnOx-loaded biochar for Pb2+ removal: Adsorption performance and possible mechanism [J].
Faheem ;
Yu, Hongxia ;
Liu, Jia ;
Shen, Jinyou ;
Sun, Xiuyun ;
Li, Jiansheng ;
Wang, Lianjun .
JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS, 2016, 66 :313-320