Facile fabrication of superhydrophobic filtration fabric with honeycomb structures for the separation of water and oil

被引：67

作者：

Li, Kunquan ^{[1
]}

Zeng, Xingrong ^{[1
]}

Li, Hongqiang ^{[1
]}

Lai, Xuejun ^{[1
]}

Xie, Hu ^{[1
]}

机构：

[1] S China Univ Technol, Coll Mat Sci & Engn, Guangzhou 510640, Guangdong, Peoples R China

来源：

MATERIALS LETTERS | 2014年 / 120卷

关键词：

Surfaces; Microstructure; Superhydrophobic; Water/oil separation; PDMS/SiO2; coating; POLYMERIZATION; MEMBRANES; SURFACES;

D O I：

10.1016/j.matlet.2014.01.105

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The superhydrophobic filtration fabric (SFF), with a water contact angle (WCA) higher than 150 degrees, was prepared by a facile dip-coating method through decorating the surface with poly(dimethyl siloxanes) (PDMS)/silica (SiO2) composite coating. To improve the roughness of the surface, toluene and ethanol was used as co-solvent to induce microphase separation. When the mass ratio of ethanol to toluene was 0.6, the SFF showed a high WCA of 152 degrees with some porous honeycomb structures distributed on the surface. Moreover, the as-prepared SFF showed both superhydrophobicity and superoleophilicity, and could effectively separate the mixture of water and oil. Based on the study, the separation mechanism was also proposed. (C) 2014 Elsevier B.V. All rights reserved.

引用

页码：255 / 258

页数：4

共 15 条

[1] Honeycomb structures obtained with breath figures self-assembly allow water/oil separation [J].

Bormashenko, Edward ;

Balter, Sagi ;

Bormashenko, Yelena ;

Aurbach, Doron .

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2012, 415 :394-398

[2] A super-hydrophobic and super-oleophilic coating mesh film for the separation of oil and water [J].

Feng, L ;

Zhang, ZY ;

Mai, ZH ;

Ma, YM ;

Liu, BQ ;

Jiang, L ;

Zhu, DB .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (15) :2012-2014

[3] Superhydrophobic surfaces with hierarchical structure [J].

Gao, N. ;

Yan, Y. Y. ;

Chen, X. Y. ;

Mee, D. J. .

MATERIALS LETTERS, 2011, 65 (19-20) :2902-2905

[4] Hygro-responsive membranes for effective oil-water separation [J].

Kota, Arun K. ;

Kwon, Gibum ;

Choi, Wonjae ;

Mabry, Joseph M. ;

Tuteja, Anish .

NATURE COMMUNICATIONS, 2012, 3

[5] Surface chemical and physical properties of TEOS-TBOT-PDMS hybrid materials [J].

Pena-Alonso, R. ;

Tellez, L. ;

Rubio, J. ;

Rubio, F. .

JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 2006, 38 (02) :133-145

[6] An in situ polymerization approach for the synthesis of superhydrophobic and superoleophilic nanofibrous membranes for oil-water separation [J].

Shang, Yanwei ;

Si, Yang ;

Raza, Aikifa ;

Yang, Liping ;

Mao, Xue ;

Ding, Bin ;

Yu, Jianyong .

NANOSCALE, 2012, 4 (24) :7847-7854

[7] Porous ceramic membrane with superhydrophobic and superoleophilic surface for reclaiming oil from oily water [J].

Su, Changhong ;

Xu, Youqian ;

Zhang, Wei ;

Liu, Yang ;

Li, Jun .

APPLIED SURFACE SCIENCE, 2012, 258 (07) :2319-2323

[8] FT-IR study of the hydrolysis and polymerization of tetraethyl orthosilicate and polydimethyl siloxane in the presence of tetrabutyl orthotitanate [J].

Téllez, L ;

Rubio, J ;

Rubio, F ;

Morales, E ;

Oteo, JL .

SPECTROSCOPY LETTERS, 2004, 37 (01) :11-31

[9] Methodology for Robust Superhydrophobic Fabrics and Sponges from In Situ Growth of Transition Metal/Metal Oxide Nanocrystals with Thiol Modification and Their Applications in Oil/Water Separation [J].

Wang, Ben ;

Li, Jing ;

Wang, Guiyuan ;

Liang, Weixin ;

Zhang, Yabin ;

Shi, Lei ;

Guo, Zhiguang ;

Liu, Weimin .

ACS APPLIED MATERIALS & INTERFACES, 2013, 5 (05) :1827-1839

[10] Facile Approach in Fabricating Superhydrophobic and Superoleophilic Surface for Water and Oil Mixture Separation [J].

Wang, Chuanxi ;

Yao, Tongjie ;

Wu, Jie ;

Ma, Cheng ;

Fan, Zhanxi ;

Wang, Zhaoyi ;

Cheng, Yuanrong ;

Lin, Quan ;

Yang, Bai .

ACS APPLIED MATERIALS & INTERFACES, 2009, 1 (11) :2613-2617

← 1 2 →