A new phosphorus sulfide with adamantane structure:: δ-P4S7

被引：0

作者：

Nowottnick, H ^{[1
]}

Blachnik, R ^{[1
]}

机构：

[1] Univ Osnabruck, Inst Chem, D-49069 Osnabruck, Germany

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2000年 / 626卷 / 03期

关键词：

P-31-NMR spectroscopy; phosphorus sulfides; triphenylphosphine;

D O I：

10.1002/(SICI)1521-3749(200003)626:3<611::AID-ZAAC611>3.0.CO;2-O

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

By sulfur abstraction from alpha-P4S9/P4S10 with triphenylphosphine a new phosphorus sulfide delta-P4S7 With adamantane skeleton and an additional sulfur in exo-position was identified in CS2-solution by P-31-NMR spectroscopy. Product distribution and P-31-NMR parameter are given.

引用

页码：611 / 612

页数：2

共 4 条

[1] Reactions of phosphorus sulfides (P4S5, P4S7 and P4S10) and 2,4-bis(alkylthio)-2,4-dithioxo-1,3,2 lambda(5),4 lambda(5)-dithiadiphosphetanes with dialkyldisulfides and thioacetals in the presence of iodine
Nizamov, IS
AlMetkina, LA
Garifzyanova, GG
Sergeenko, GG
Batyeva, ES
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 1995, 102 (1-4): : 71 - 81
[2] THE MOLECULAR COMPOSITION OF SOLIDIFIED PHOSPHORUS-SULFUR MELTS AND THE CRYSTAL-STRUCTURE OF BETA-P4S6
BLACHNIK, R
PEUKERT, U
CZEDIWODA, A
ENGELEN, B
BOLDT, K
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1995, 621 (10): : 1637 - 1643
[3] The Crystal and Molecular Structure of γ-P4S6
Roedl, Thomas
Pfitzner, Arno
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2011, 637 (11): : 1507 - 1510
[4] New orthopalladated complexes of phosphorus ylides: Crystal structure of [Pd{CH{P(C7H6)(p-tolyl)2}COCH3}Cl{P(p-tolyl)3}]
Sabounchei, Seyyed Javad
Nemattalab, Hassan
Akhlaghi, Fateme
Khavasi, Hamid Reza
POLYHEDRON, 2008, 27 (15) : 3275 - 3279

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