A study of poly(4-vinylpyridine)-supported ruthenate in the oxidation of alcohols

被引:8
作者
Friedrich, Holger B. [1 ]
Singh, Nirad [1 ]
机构
[1] Univ KwaZulu Natal, Howard Coll, Sch Chem, ZA-4041 Durban, South Africa
基金
新加坡国家研究基金会;
关键词
alcohols; oxidation; polymer-supported; ruthenium;
D O I
10.1007/s10562-006-0099-6
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Sodium ruthenate was supported on 2% and 25% cross-linked poly(4-vinylpyridine). These compounds were found to be efficient and selective catalysts for the room temperature oxidation of internal and external alcohols to aldehydes and ketones, respectively. The catalysts were active with a wide range of co-oxidants and no over-oxidation products were observed.
引用
收藏
页码:61 / 70
页数:10
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