Ferric Hydrogen Sulfate as an Efficient Heterogeneous Catalyst for Environmentally Friendly Greener Synthesis of 1,8-Dioxo-Octahydroxanthenes

被引:38
作者
Shaterian, Hamid Reza [1 ]
Hosseinian, Asghar [1 ]
Ghashang, Majid [1 ]
机构
[1] Univ Sistan & Baluchistan, Dept Chem, Fac Sci, Zahedan, Iran
关键词
Fe(HSO4)(3); dimedone; heterogeneous catalyst; 1,8-dioxo-octahydroxanthene; SOLVENT-FREE CONDITIONS; AQUEOUS-MEDIA; DERIVATIVES; CONDENSATION; KETONES; ACID;
D O I
10.3906/kim-0803-2
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Ferric hydrogen sulfate was used as an environmentally friendly heterogeneous acidic catalyst for the greener, 1-pot, 3-component synthesis of 1,8-dioxo-octahydroxanthene via condensation reactions between aromatic aldehydes and dimedone under solvent-free thermal and microwave irradiation as well as in aqueous media conditions in short periods of times with excellent yields. The catalyst was easily separated in simple work-up and was recycled several times without loss of reactivity under the described reaction conditions.
引用
收藏
页码:233 / 240
页数:8
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