Polymerization-Induced Self-Assembly of Block Copolymer Nano-objects via RAFT Aqueous Dispersion Polymerization

被引：979

作者：

Warren, Nicholas J. ^{[1
]}

Armes, Steven P. ^{[1
]}

机构：

[1] Univ Sheffield, Dept Chem, Sheffield S3 7HF, S Yorkshire, England

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2014年 / 136卷 / 29期

基金：

英国工程与自然科学研究理事会;

关键词：

POLYELECTROLYTE-STABILIZED NANOPARTICLES; LIVING RADICAL POLYMERIZATION; CORE-SHELL NANOGELS; DIBLOCK COPOLYMER; METHYL-METHACRYLATE; PHASE-DIAGRAM; CONTROL AGENT; MICELLES; POLYMERSOMES; VESICLES;

D O I：

10.1021/ja502843f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In this Perspective, we discuss the recent development of polymerization-induced self-assembly mediated by reversible addition fragmentation chain transfer (RAFT) aqueous dispersion polymerization. This approach has quickly become a powerful and versatile technique for the synthesis of a wide range of bespoke organic diblock copolymer nano-objects of controllable size, morphology, and surface functionality. Given its potential scalability, such environmentally-friendly formulations are expected to offer many potential applications, such as novel Pickering emulsifiers, efficient micro-encapsulation vehicles, and sterilizable thermo-responsive hydrogels for the cost-effective long-term storage of mammalian cells.

引用

页码：10174 / 10185

页数：12

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