Influence of the hydration by the environmental humidity on the metallic speciation and the photocatalytic activity of Cr/MCM-41

被引：8

作者：

Elias, Veronica R. ^{[1
]}

Sabre, Ema V. ^{[1
]}

Winkler, Elin L. ^{[2
]}

Andrini, Leandro ^{[3
]}

Requejo, Felix G. ^{[3
,4
]}

Casuscelli, Sandra G. ^{[1
]}

Eimer, Griselda A. ^{[1
]}

机构：

[1] Ctr Invest & Tecnol Quim CITeQ UTN CONICET, RA-5016 Cordoba, Argentina

[2] CNEA CONICET, Ctr Atom Bariloche, RA-8400 San Carlos De Bariloche, Argentina

[3] UNLP CCT CONICET La Plata, Inst Fisicoquim Teor & Aplicada INIFTA, RA-1900 La Plata, Argentina

[4] UNLP, Fac Ciencias Exactas, Dto Fis, La Plata, Buenos Aires, Argentina

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 2014年 / 213卷

关键词：

Environmental humidity; Chromium species; TiO2; cover; Photoactivity; MCM-41; MOLECULAR-SIEVES; CHROMIUM; ABSORPTION; MCM-41; DEHYDROGENATION; SPECTROSCOPY; COORDINATION; DEGRADATION; CATALYSTS; ACID;

D O I：

10.1016/j.jssc.2014.03.002

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The influence of the environmental humidity on the Cr species deposited on inorganic supports like MCM-41 silicates was analyzed by UV-vis Diffuse Reflectance (UV-vis RD), Electronic Spin Resonance (ESR) and X-ray near-edge ()CANES) spectroscopy. Metal speciation could be inferred, finding that prolonged exposure periods under environmental humidity provoked the reduction of the active Cr6+ species and thus, the decrease of the Cr/MCM-41 photoactivity. After the Ti loading over the Cr modified samples, Cr species and the photoactivity were not notably influenced by the humidity exposure. Thus, it could be concluded that the presence of Ti is important because the TiO2 cover protects the oxidized Cr species, stabilizing them. (C) 2014 Elsevier Inc. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/3.0/).

引用

页码：229 / 234

页数：6

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