Preparation of electrochemically reduced graphene oxide/multi-wall carbon nanotubes hybrid film modified electrode, and its application to amperometric sensing of rutin

被引:7
作者
Yang, Suling [1 ]
Li, Gang [1 ]
Hu, Meifang [1 ]
Qu, Lingbo [1 ,2 ]
机构
[1] Anyang Normal Univ, Coll Chem & Chem Engn, Anyang 455002, Peoples R China
[2] Henan Univ Technol, Chem & Chem Engn Sch, Zhengzhou 450001, Peoples R China
基金
中国国家自然科学基金;
关键词
Multi-wall carbon nanotubes; grapheme; rutin; electroanalyisis; PERFORMANCE; REDUCTION; SENSOR;
D O I
10.1007/s12039-014-0654-4
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Through a facile electrochemical method, we prepared an electrochemically reduced graphene oxide (ERGO)/multi-wall carbon nanotubes (MWNTs) hybrid film modified glassy carbon electrode (GCE), and characterized it by Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM) and x-ray diffraction (XRD) The experimental results demonstrated that ERGO-MWNTs/GCE exhibited excellent electrocatalytic activity toward rutin as evidenced by the significant enhancement of redox peak currents in comparison with a bare GCE, ERGO/GCE and MWNTs/GCE. This method has been applied for the direct determination of rutin in real samples with satisfactory results.
引用
收藏
页码:1021 / 1029
页数:9
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