Preparation of electrochemically reduced graphene oxide/multi-wall carbon nanotubes hybrid film modified electrode, and its application to amperometric sensing of rutin

被引:7
作者
Yang, Suling [1 ]
Li, Gang [1 ]
Hu, Meifang [1 ]
Qu, Lingbo [1 ,2 ]
机构
[1] Anyang Normal Univ, Coll Chem & Chem Engn, Anyang 455002, Peoples R China
[2] Henan Univ Technol, Chem & Chem Engn Sch, Zhengzhou 450001, Peoples R China
基金
中国国家自然科学基金;
关键词
Multi-wall carbon nanotubes; grapheme; rutin; electroanalyisis; PERFORMANCE; REDUCTION; SENSOR;
D O I
10.1007/s12039-014-0654-4
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Through a facile electrochemical method, we prepared an electrochemically reduced graphene oxide (ERGO)/multi-wall carbon nanotubes (MWNTs) hybrid film modified glassy carbon electrode (GCE), and characterized it by Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM) and x-ray diffraction (XRD) The experimental results demonstrated that ERGO-MWNTs/GCE exhibited excellent electrocatalytic activity toward rutin as evidenced by the significant enhancement of redox peak currents in comparison with a bare GCE, ERGO/GCE and MWNTs/GCE. This method has been applied for the direct determination of rutin in real samples with satisfactory results.
引用
收藏
页码:1021 / 1029
页数:9
相关论文
共 33 条
[1]  
Bard A.J, 2002, Student Solutions Manual to accompany Electrochemical Methods: Fundamentals and Applicaitons, V2e
[2]   Sensitive determination of rutin using a Nafion/PMB/Graphene composite-modified glassy electrode [J].
Cai, Feng ;
Xia, Jian-fei ;
Wang, Zong-hua ;
Xia, Yan-zhi ;
Zhang, Fei-fei ;
Xia, Lin-hua .
BIOTECHNOLOGY, CHEMICAL AND MATERIALS ENGINEERING II, PTS 1 AND 2, 2013, 641-642 :566-+
[3]   Bulk production of a new form of sp2 carbon:: Crystalline graphene nanoribbons [J].
Campos-Delgado, Jessica ;
Romo-Herrera, Jose Manuel ;
Jia, Xiaoting ;
Cullen, David A. ;
Muramatsu, Hiroyuki ;
Kim, Yoong Ahm ;
Hayashi, Takuya ;
Ren, Zhifeng ;
Smith, David J. ;
Okuno, Yu ;
Ohba, Tomonori ;
Kanoh, Hirofumi ;
Kaneko, Katsumi ;
Endo, Morinobu ;
Terrones, Humberto ;
Dresselhaus, Mildred S. ;
Terrones, Mauriclo .
NANO LETTERS, 2008, 8 (09) :2773-2778
[4]   A high performance electrochemical sensor for acetaminophen based on single-walled carbon nanotube-graphene nanosheet hybrid films [J].
Chen, Xu ;
Zhu, June ;
Xi, Qian ;
Yang, Wensheng .
SENSORS AND ACTUATORS B-CHEMICAL, 2012, 161 (01) :648-654
[5]   Anodic Electrogenerated Chemiluminescence Behavior of Graphite-Like Carbon Nitride and Its Sensing for Rutin [J].
Cheng, Changming ;
Huang, Ying ;
Wang, Jun ;
Zheng, Baozhan ;
Yuan, Hongyan ;
Xiao, Dan .
ANALYTICAL CHEMISTRY, 2013, 85 (05) :2601-2605
[6]   A review on plant-based rutin extraction methods and its pharmacological activities [J].
Chua, Lee Suan .
JOURNAL OF ETHNOPHARMACOLOGY, 2013, 150 (03) :805-817
[7]   A Green Approach to the Synthesis of Graphene Nanosheets [J].
Guo, Hui-Lin ;
Wang, Xian-Fei ;
Qian, Qing-Yun ;
Wang, Feng-Bin ;
Xia, Xing-Hua .
ACS NANO, 2009, 3 (09) :2653-2659
[8]   PREPARATION OF GRAPHITIC OXIDE [J].
HUMMERS, WS ;
OFFEMAN, RE .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1958, 80 (06) :1339-1339
[9]   HELICAL MICROTUBULES OF GRAPHITIC CARBON [J].
IIJIMA, S .
NATURE, 1991, 354 (6348) :56-58
[10]   Electrochemical-Assisted Encapsulation of Catechol on a Multiwalled Carbon Nanotube Modified Electrode [J].
Kumar, Annamalai Senthil ;
Swetha, Puchakayala .
LANGMUIR, 2010, 26 (10) :6874-6877