Radicals derived from Lewis acid/base pairs

被引：112

作者：

Liu, Liu Leo ^{[1
]}

Stephan, Douglas W. ^{[1
]}

机构：

[1] Univ Toronto, Dept Chem, 80 St George St, Toronto, ON M5S3H6, Canada

来源：

CHEMICAL SOCIETY REVIEWS | 2019年 / 48卷 / 13期

基金：

加拿大自然科学与工程研究理事会;

关键词：

ONE-ELECTRON OXIDATION; HOMOLYTIC CLEAVAGE; REACTIVITY; REDUCTION; TRIS(PENTAFLUOROPHENYL)BORANE; B(C6F5)(3); TEMPO; BORYLATION; COMPLEXES; MOLECULE;

D O I：

10.1039/c8cs00940f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

While conventional approaches to stabilizing main group radicals have involved the use of Lewis acids or bases, this tutorial review focuses on new avenues to main group radicals derived from combinations of donor and acceptor molecules. Reactions involving the use of both classical Lewis acid-base adducts and frustrated Lewis pair systems are discussed and the subsequent reactivity is considered.

引用

页码：3454 / 3463

页数：10

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