Cascade Reactions Catalyzed by Bionanostructures

被引：86
作者：
Filice, Marco [1 ]
Palomo, Jose M. [1 ]
机构：
[1] Inst Catilisis CSIC, Dept Biocatalisis, Madrid 28049, Spain
来源：
ACS CATALYSIS | 2014年 / 4卷 / 05期
关键词：
nanoparticles; nanostructures; biohybrids; cascade catalysis; tandem reaction; domino reaction; COMPLEX WOOL-PD; AMPLIFICATION STRATEGY; HETEROGENEOUS CATALYST; GOLD NANOPARTICLES; TANDEM CATALYSIS; METAL; PROTEIN; EFFICIENT; ENZYME; NANOCRYSTALS;
D O I：
10.1021/cs401005y
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Cascade reactions are an emerging technology in organic chemistry, introducing elegance and efficiency to synthetic strategies. This Review provides an overview of the novel and recent achievements in cascade processes catalyzed by bionanostructures. The examples here selected demonstrate the advances related to the application of heterogeneous nanocatalysts nanostructures and biomolecules combined by different manner in efficient cascade processes. Metallic nanoparticles supported on biomolecules, multienzymatic systems or bionanohybrid structures with multicatalytic activities (containing both organometallic and biocatalytic activity) were selectively and efficiently used alone or in cooperative fashion. This Review highlights examples of efficient and interesting catalytic cascade processes in organic chemistry, ultrasensitive biosensing, or energy storage and conversion, underscoring their tremendous future potential in chemical synthesis.
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收藏
页码：1588 / 1598
页数：11
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