Green photochemistry:: solar-chemical synthesis of Juglone with medium concentrated sunlight

被引：70
作者：
Oelgemoeller, Michael [1 ]
Healy, Niall
de Oliveira, Lamark
Jung, Christian
Mattay, Jochen
机构：
[1] Dublin City Univ, Sch Chem Sci, Dublin 9, Ireland
[2] Natl Inst Cellular Biotechnol, Dublin 9, Ireland
[3] Deutsch Zentrum Luft & Raumfahrt eV, DLR, D-51147 Cologne, Germany
[4] Univ Bielefeld, Fak Chem, D-33501 Bielefeld, Germany
来源：
GREEN CHEMISTRY | 2006年 / 8卷 / 09期
关键词：
D O I：
10.1039/b605906f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Dye sensitized photooxygenations of 1,5-dihydroxynaphthalene were investigated with soluble and solid-supported sensitizers and moderately concentrated sunlight. Moderate to good yields up to 79% of 5-hydroxy-1,4-naphthoquinone (Juglone) were achieved on multiple gram-scales after just 4 h of illumination. The mild and environmentally friendly reaction conditions make this application particularly attractive for 'green photochemistry'.
引用
收藏
页码：831 / 834
页数：4
相关论文
共 55 条
  • [41] Twentieth century developments in photochemistry. Brief historical sketches
    Roth, HD
    [J]. PURE AND APPLIED CHEMISTRY, 2001, 73 (03) : 395 - 403
  • [42] THE BEGINNINGS OF ORGANIC-PHOTOCHEMISTRY
    ROTH, HD
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1989, 28 (09): : 1193 - 1207
  • [43] Solar light induced photocatalytic oxidation of benzyl alcohol using heteropolyoxometalate catalysts of the type [S2M18O62]4-
    Rüther, T
    Bond, AM
    Jackson, WR
    [J]. GREEN CHEMISTRY, 2003, 5 (04) : 364 - 366
  • [44] POLYMER-BASED SENSITIZERS FOR PHOTOOXIDATIONS .2.
    SCHAAP, AP
    THAYER, AL
    BLOSSEY, EC
    NECKERS, DC
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (13) : 3741 - 3745
  • [45] Schiel C, 1998, J INFORM REC, V24, P257
  • [46] Green photochemistry:: the solar-chemical 'photo-Friedel-Crafts acylation' of quinones
    Schiel, C
    Oelgemöller, M
    Ortner, J
    Mattay, J
    [J]. GREEN CHEMISTRY, 2001, 3 (05) : 224 - 228
  • [47] Schiel C, 2001, SYNTHESIS-STUTTGART, P1275
  • [48] Shinkarenko N.V., 1981, RUSS CHEM REV+, V50, P220, DOI DOI 10.1070/RC1981V050N03ABEH002587
  • [49] Photooxygenations of 1-naphthols:: an environmentally friendly access to 1,4-naphthoquinones
    Suchard, O
    Kane, R
    Roe, BJ
    Zimmerman, E
    Jung, C
    Waske, PA
    Mattay, J
    Oelgemöller, M
    [J]. TETRAHEDRON, 2006, 62 (07) : 1467 - 1473
  • [50] Synthetic pathways and processes in green chemistry. Introductory overview
    Tundo, P
    Anastas, P
    Black, DS
    Breen, J
    Collins, T
    Memoli, S
    Miyamoto, J
    Polyakoff, M
    Tumas, W
    [J]. PURE AND APPLIED CHEMISTRY, 2000, 72 (07) : 1207 - 1228
123456