Green photochemistry:: solar-chemical synthesis of Juglone with medium concentrated sunlight

被引：72

作者：

Oelgemoeller, Michael ^{[1
]}

Healy, Niall

de Oliveira, Lamark

Jung, Christian

Mattay, Jochen

机构：

[1] Dublin City Univ, Sch Chem Sci, Dublin 9, Ireland

[2] Natl Inst Cellular Biotechnol, Dublin 9, Ireland

[3] Deutsch Zentrum Luft & Raumfahrt eV, DLR, D-51147 Cologne, Germany

[4] Univ Bielefeld, Fak Chem, D-33501 Bielefeld, Germany

来源：

GREEN CHEMISTRY | 2006年 / 8卷 / 09期

关键词：

D O I：

10.1039/b605906f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Dye sensitized photooxygenations of 1,5-dihydroxynaphthalene were investigated with soluble and solid-supported sensitizers and moderately concentrated sunlight. Moderate to good yields up to 79% of 5-hydroxy-1,4-naphthoquinone (Juglone) were achieved on multiple gram-scales after just 4 h of illumination. The mild and environmentally friendly reaction conditions make this application particularly attractive for 'green photochemistry'.

引用

页码：831 / 834

页数：4

共 55 条

[1] Green chemistry and photochemistry were born at the same time [J].

Albini, A ;

Fagnoni, M .

GREEN CHEMISTRY, 2004, 6 (01) :1-6

[2] Environment-friendly organic synthesis. The photochemical approach [J].

Albini, A ;

Fagnoni, M ;

Mella, M .

PURE AND APPLIED CHEMISTRY, 2000, 72 (07) :1321-1326

[3]

Anastas P. T., 1998, GREEN CHEM THEORY PR

[4] The synthesis of kermesic acid and isokermesic acid derivatives and of related dihydroxyanthraquinones [J].

Bingham, SJ ;

Tyman, JHP .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1997, (24) :3637-3642

[5] POLYMER-BASED SENSITIZERS FOR PHOTOOXIDATIONS [J].

BLOSSEY, EC ;

NECKERS, DC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1973, 95 (17) :5820-5822

[6] Recent advances in the synthesis of angucyclines [J].

Carreño, MC ;

Urbano, A .

SYNLETT, 2005, (01) :1-25

[7]

Ciamician G, 1912, Science, V36, P385, DOI 10.1126/science.36.926.385

[8] Advances in singlet oxygen chemistry [J].

Clennan, EL ;

Pace, A .

TETRAHEDRON, 2005, 61 (28) :6665-6691

[9] Formal radical cyclization onto benzene rings:: a general method and its use in the synthesis of ent-nocardione A [J].

Clive, DLJ ;

Fletcher, SP ;

Liu, DZ .

JOURNAL OF ORGANIC CHEMISTRY, 2004, 69 (10) :3282-3293

[10]

Contant P, 1999, SYNTHESIS-STUTTGART, P821

← 1 2 3 4 5 6 →