Cycling behavior of poly(vinylidene fluoride-hexafluoro propylene) (PVdF-HFP) membranes prepared by phase inversion method

被引：36

作者：

Stephan, AM ^{[1
]}

Renganathan, NG

Gopukumar, S

Dale-Teeters

机构：

[1] Cent Electrochem Res Inst, Adv Batteries Div, Karaikkudi 630006, Tamil Nadu, India

[2] Univ Tulsa, Dept Chem, Tulsa, OK 74104 USA

来源：

MATERIALS CHEMISTRY AND PHYSICS | 2004年 / 85卷 / 01期

关键词：

phase inversion; non-solvent; scanning electron microscopy; BET surface area; charge-discharge studies;

D O I：

10.1016/j.matchemphys.2003.11.038

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

A novel highly porous poly(vinylidene fluoride-hexafluoropropylene) (PVdF-HFP) membrane was prepared by phase inversion method with 1-butanol or methanol as non-solvent. These films where characterized by ionic conductivity, SEM and nitrogen adsorption/desorption analysis. The prepared membranes were employed as separator in LiA1(0.01) Co0.99O2/Li cells and their charge-discharge performances are presented. Although, these membranes vary slightly in the physical properties like, morphology and surface area no discernible changes could be seen in charge-discharge studies. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：6 / 11

页数：6

共 21 条

[1] KINETICS AND STABILITY OF THE LITHIUM ELECTRODE IN POLY(METHYLMETHACRYLATE)-BASED GEL ELECTROLYTES [J].

APPETECCHI, GB ;

CROCE, F ;

SCROSATI, B .

ELECTROCHIMICA ACTA, 1995, 40 (08) :991-997

[2]

Armand M. B., 1979, Fast Ion Transport in Solids. Electrodes and Electrolytes, P131

[3] MICROSCOPIC INVESTIGATION OF IONIC-CONDUCTIVITY IN ALKALI-METAL SALTS POLY(ETHYLENE OXIDE) ADDUCTS [J].

BERTHIER, C ;

GORECKI, W ;

MINIER, M ;

ARMAND, MB ;

CHABAGNO, JM ;

RIGAUD, P .

SOLID STATE IONICS, 1983, 11 (01) :91-95

[4] PERFORMANCE OF ACRYLATE-POLY(ETHYLENE OXIDE) POLYMER ELECTROLYTES IN LITHIUM BATTERIES [J].

BORKOWSKA, R ;

LASKOWSKI, J ;

PLOCHARSKI, J ;

PRZYLUSKI, J ;

WIECZOREK, W .

JOURNAL OF APPLIED ELECTROCHEMISTRY, 1993, 23 (10) :991-995

[5] Identification of cathode materials for lithium batteries guided by first-principles calculations [J].

Ceder, G ;

Chiang, YM ;

Sadoway, DR ;

Aydinol, MK ;

Jang, YI ;

Huang, B .

NATURE, 1998, 392 (6677) :694-696

[6] INTERFACIAL PHENOMENA IN POLYMER-ELECTROLYTE CELLS - LITHIUM PASSIVATION AND CYCLEABILITY [J].

CROCE, F ;

SCROSATI, B .

JOURNAL OF POWER SOURCES, 1993, 43 (1-3) :9-19

[7] COMPLEXES OF ALKALI-METAL IONS WITH POLY(ETHYLENE OXIDE) [J].

FENTON, DE ;

PARKER, JM ;

WRIGHT, PV .

POLYMER, 1973, 14 (11) :589-589

[8]

GOZDZ AS, 1997, Patent No. 5540741

[9] LiAlxCo1-xO2 as 4 V cathodes for lithium ion batteries [J].

Huang, HT ;

Rao, GVS ;

Chowdari, BVR .

JOURNAL OF POWER SOURCES, 1999, 81 :690-695

[10] Studies of some poly(vinylidene fluoride) electrolytes [J].

Jiang, Z ;

Carroll, B ;

Abraham, KM .

ELECTROCHIMICA ACTA, 1997, 42 (17) :2667-2677

← 1 2 3 →