Influence of annealing temperature on physical properties of Sn-doped CdO thin films by nebulized spray pyrolysis technique

被引:24
作者
Anitha, M. [1 ,3 ]
Saravanakumar, K. [2 ]
Anitha, N. [1 ]
Kulandaisamy, I. [4 ]
Amalraj, L. [1 ]
机构
[1] VHNSN Coll Autonomous, Res Dept Phys, Virudunagar 626001, Tamil Nadu, India
[2] VHNSN Coll Autonomous, Dept Chem, Virudunagar 626001, Tamil Nadu, India
[3] Sri Vidhya Coll Arts & Sci, Dept Phys, Virudunagar 626001, Tamil Nadu, India
[4] Arul Anandar Coll, PG & Res Dept Phys, Madurai 625514, Tamil Nadu, India
来源
MATERIALS SCIENCE AND ENGINEERING B-ADVANCED FUNCTIONAL SOLID-STATE MATERIALS | 2019年 / 243卷
关键词
Thin films; CdO; Crystal structure; Optical properties; Luminescence; Electrical properties; Solar cell; OPTICAL-PROPERTIES; ELECTRICAL-PROPERTIES; ZNO-CDO; TRANSPARENT; FABRICATION;
D O I
10.1016/j.mseb.2019.03.018
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Tin (Sn) doped cadmium oxide (CdO) thin films deposited onto the glass substrates by nebulized spray pyrolysis technique (NSP) were annealed for 20 min at different temperatures of 473-548 K in steps of 25 K. X-ray diffraction study showed that all these thin films were polycrystalline with major reflection along (1 1 1) plane and the crystallite size had increased at elevated annealing temperatures. From SEM images, it was found that annealing causes notable changes in the surface morphology. The oxidation states of Cd2+, O2- and Sn4+ were confirmed by X-ray photoelectron spectroscopy analysis. These films were found to have direct band gap energy lying in the range of 2.55-2.42 eV and the average transmittance varies from 73 to 87% with various annealing temperatures. The CdO thin films annealed at 523 K exhibited the lowest resistivity (1.03 x 10(-4) Omega cm).
引用
收藏
页码:54 / 64
页数:11
相关论文
共 58 条
[51]   Characterization of spray pyrolytically deposited high mobility praseodymium doped CdO thin films [J].
Velusamy, P. ;
Babu, R. Ramesh ;
Ramamurthi, K. ;
Elangovan, E. ;
Viegas, J. ;
Dahlem, M. S. ;
Arivanandhan, M. .
CERAMICS INTERNATIONAL, 2016, 42 (11) :12675-12685
[52]   Highly transparent conducting cerium incorporated CdO thin films deposited by a spray pyrolytic technique [J].
Velusamy, P. ;
Babu, R. Ramesh ;
Ramamurthi, K. ;
Dahlem, M. S. ;
Elangovan, E. .
RSC ADVANCES, 2015, 5 (124) :102741-102749
[53]   Structural, microstructural, optical and electrical properties of spray deposited rare-earth metal (Sm) ions doped CdO thin films [J].
Velusamy, P. ;
Babu, R. Ramesh ;
Ramamurthi, K. ;
Viegas, J. ;
Elangovan, E. .
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2015, 26 (06) :4152-4164
[54]   Photoluminescence study of ZnO films prepared by thermal oxidation of Zn metallic films in air [J].
Wang, YG ;
Lau, SP ;
Lee, HW ;
Yu, SF ;
Tay, BK ;
Zhang, XH ;
Hng, HH .
JOURNAL OF APPLIED PHYSICS, 2003, 94 (01) :354-358
[55]   Fabrication and characterization of nanocrystalline n-CdO/p-Si as a solar cell [J].
Zaien, M. ;
Ahmed, N. M. ;
Hassan, Z. .
SUPERLATTICES AND MICROSTRUCTURES, 2012, 52 (04) :800-806
[56]   Electrical and optical properties of tin-doped CdO films deposited by atmospheric metalorganic chemical vapor deposition [J].
Zhao, ZY ;
Morel, DL ;
Ferekides, CS .
THIN SOLID FILMS, 2002, 413 (1-2) :203-211
[57]   Optical and electrical properties of Sn-doped CdO thin films obtained by pulse laser deposition [J].
Zheng, B. J. ;
Lian, J. S. ;
Zhao, L. ;
Jiang, Q. .
VACUUM, 2011, 85 (09) :861-865
[58]   Transparent and conductive indium doped cadmium oxide thin films prepared by pulsed filtered cathodic arc deposition [J].
Zhu, Yuankun ;
Mendelsberg, Rueben J. ;
Zhu, Jiaqi ;
Han, Jiecai ;
Anders, Andre .
APPLIED SURFACE SCIENCE, 2013, 265 :738-744