Fe3O4@silica-MCM-41@DABCO: A novel magnetically reusable nanostructured catalyst for clean in situ synthesis of substituted 2-aminodihydropyrano[3,2-b]pyran-3-cyano

被引：31

作者：

Aghbash, Khadijeh Ojaghi ^{[1
]}

Pesyan, Nader Noroozi ^{[1
]}

Batmani, Hana ^{[1
]}

机构：

[1] Urmia Univ, Fac Chem, Dept Organ Chem, Orumiyeh 57159, Iran

来源：

APPLIED ORGANOMETALLIC CHEMISTRY | 2019年 / 33卷 / 11期

关键词：

2-amino-4; 8-dihydropyrano[3; 2-b]pyran-3-carbonitrile; azido kojic acid; Fe3O4@MCM-41@DABCO; Michael addition; nanocatalyst; ACID-FUNCTIONALIZED MCM-41; HETEROGENEOUS CATALYST; CONTROLLABLE SYNTHESIS; MESOPOROUS MATERIALS; RECYCLABLE CATALYST; HIGHLY EFFICIENT; NANOPARTICLES; SILICA; DABCO; ANTIOXIDANT;

D O I：

10.1002/aoc.5227

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

DABCO (1,4-diazabicyclo[2.2.2]octane)-modified magnetite with silica-MCM-41 shell (Fe3O4@silica-MCM-41@DABCO) as an effective, magnetic and novel heterogeneous reusable nanocatalyst was synthesized and analysed using various techniques. Evaluation of the catalytic activity of this nanocatalyst was performed in the clean synthesis of substituted 2-aminodihydropyrano[3,2-b]pyran-3-cyano in high yields via in situ reaction of azido kojic acid, malononitrile and various aldehydes.

引用

页数：12

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