Copper-Oxygen Complexes Revisited: Structures, Spectroscopy, and Reactivity

被引：551

作者：

Elwell, Courtney E. ^{[1
]}

Gagnon, Nicole L. ^{[1
]}

Neisen, Benjamin D. ^{[1
]}

Dhar, Debanjan ^{[1
]}

Spaeth, Andrew D. ^{[1
]}

Yee, Gereon M. ^{[1
]}

Tolman, William B. ^{[1
]}

机构：

[1] Univ Minnesota, Dept Chem, Ctr Met Biocatalysis, 207 Pleasant St SE, Minneapolis, MN 55455 USA

来源：

CHEMICAL REVIEWS | 2017年 / 117卷 / 03期

基金：

美国国家卫生研究院;

关键词：

PARTICULATE METHANE MONOOXYGENASE; CYTOCHROME-C-OXIDASE; ALPHA-HYDROXYLATING MONOOXYGENASE; O BOND-CLEAVAGE; DOPAMINE BETA-MONOOXYGENASE; BRIDGED DICOPPER(II) COMPLEXES; HYDROGEN-ATOM TRANSFER; ACTIVE-SITE MODELS; X-RAY-ABSORPTION; N-DONOR LIGANDS;

D O I：

10.1021/acs.chemrev.6b00636

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A longstanding research goal has been to understand the nature and role of copper oxygen intermediates within copper-containing enzymes and abiological catalysts. Synthetic chemistry has played a pivotal role in highlighting the viability of proposed intermediates and expanding the library of known copper oxygen cores. In addition to the number of new complexes that have been synthesized since the previous reviews on this topic in this journal (Mirica, L. M.; Ottenwaelder, X.; Stack, T. D. P. Chem. Rev. 2004, 104, 1013-1046 and Lewis, E. A.; Tolman, W. B. Chem. Rev. 2004, 104, 1047-1076), the field has seen significant expansion in the (1) range of cores synthesized and characterized, (2) amount of mechanistic work performed, particularly in the area of organic substrate oxidation, and (3) use of computational methods for both the corroboration and prediction of proposed intermediates. The scope of this review has been limited to well-characterized examples of copper oxygen species but seeks to provide a thorough picture of the spectroscopic characteristics and reactivity trends of the copper oxygen cores discussed.

引用

页码：2059 / 2107

页数：49

共 411 条

[101] [CuO]+ and [CuOH]2+ Complexes: Intermediates in Oxidation Catalysis? [J].